Dibromido(di-2-pyridylamine-κ(2) N,N′)mercury(II)

In the mol­ecule of the title compound, [HgBr(2)(C(10)H(9)N(3))], the Hg(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Br atoms. In the crystal structure, inter­molecular N—H⋯Br hydrogen bonds link the mol...

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Autores principales: Kalateh, Khadijeh, Norouzi, Ali, Ebadi, Amin, Ahmadi, Roya, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960074/
https://www.ncbi.nlm.nih.gov/pubmed/21581184
http://dx.doi.org/10.1107/S1600536808038129
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author Kalateh, Khadijeh
Norouzi, Ali
Ebadi, Amin
Ahmadi, Roya
Amani, Vahid
author_facet Kalateh, Khadijeh
Norouzi, Ali
Ebadi, Amin
Ahmadi, Roya
Amani, Vahid
author_sort Kalateh, Khadijeh
collection PubMed
description In the mol­ecule of the title compound, [HgBr(2)(C(10)H(9)N(3))], the Hg(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Br atoms. In the crystal structure, inter­molecular N—H⋯Br hydrogen bonds link the mol­ecules into centrosymmetric dimers. There are π–π contacts between the pyridine rings [centroid–centroid distances = 3.9662 (5) and 3.9321 (4) Å]. There also exists a C—H⋯π contact between the pyridine CH group and a pyridine ring.
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spelling pubmed-29600742010-12-30 Dibromido(di-2-pyridylamine-κ(2) N,N′)mercury(II) Kalateh, Khadijeh Norouzi, Ali Ebadi, Amin Ahmadi, Roya Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mol­ecule of the title compound, [HgBr(2)(C(10)H(9)N(3))], the Hg(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Br atoms. In the crystal structure, inter­molecular N—H⋯Br hydrogen bonds link the mol­ecules into centrosymmetric dimers. There are π–π contacts between the pyridine rings [centroid–centroid distances = 3.9662 (5) and 3.9321 (4) Å]. There also exists a C—H⋯π contact between the pyridine CH group and a pyridine ring. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2960074/ /pubmed/21581184 http://dx.doi.org/10.1107/S1600536808038129 Text en © Kalateh et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kalateh, Khadijeh
Norouzi, Ali
Ebadi, Amin
Ahmadi, Roya
Amani, Vahid
Dibromido(di-2-pyridylamine-κ(2) N,N′)mercury(II)
title Dibromido(di-2-pyridylamine-κ(2) N,N′)mercury(II)
title_full Dibromido(di-2-pyridylamine-κ(2) N,N′)mercury(II)
title_fullStr Dibromido(di-2-pyridylamine-κ(2) N,N′)mercury(II)
title_full_unstemmed Dibromido(di-2-pyridylamine-κ(2) N,N′)mercury(II)
title_short Dibromido(di-2-pyridylamine-κ(2) N,N′)mercury(II)
title_sort dibromido(di-2-pyridylamine-κ(2) n,n′)mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960074/
https://www.ncbi.nlm.nih.gov/pubmed/21581184
http://dx.doi.org/10.1107/S1600536808038129
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AT ebadiamin dibromidodi2pyridylaminek2nnmercuryii
AT ahmadiroya dibromidodi2pyridylaminek2nnmercuryii
AT amanivahid dibromidodi2pyridylaminek2nnmercuryii

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