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(E)-N′-(5-Chloro-2-hydroxybenzylidene)-p-toluenesulfonohydrazide
The title compound, C(14)H(13)ClN(2)O(3)S, features an intramolecular O—H⋯N hydrogen bond which generates an S(6) ring motif. Intermolecular N—H⋯O hydrogen bonds and C—H⋯O close contacts link neighbouring molecules forming R (2) (2)(13) ring motifs. In the crystal structure, molecules are furthe...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960077/ https://www.ncbi.nlm.nih.gov/pubmed/21581392 http://dx.doi.org/10.1107/S1600536808038695 |
Sumario: | The title compound, C(14)H(13)ClN(2)O(3)S, features an intramolecular O—H⋯N hydrogen bond which generates an S(6) ring motif. Intermolecular N—H⋯O hydrogen bonds and C—H⋯O close contacts link neighbouring molecules forming R (2) (2)(13) ring motifs. In the crystal structure, molecules are further linked by C—H⋯Cl interactions, forming one-dimensional extended chains along the c axis. The dihedral angle between the two benzene rings is 86.06 (3)°. The crystal structure is further stabilized by weak intermolecular π–π interactions [interplanar stacking distance = 3.357 (7) Å]. |
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