(E)-N′-(5-Chloro-2-hydroxy­benzyl­idene)-p-toluene­sulfonohydrazide

The title compound, C(14)H(13)ClN(2)O(3)S, features an intra­molecular O—H⋯N hydrogen bond which generates an S(6) ring motif. Inter­molecular N—H⋯O hydrogen bonds and C—H⋯O close contacts link neighbouring mol­ecules forming R (2) (2)(13) ring motifs. In the crystal structure, mol­ecules are furthe...

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Detalles Bibliográficos
Autores principales: Kia, Reza, Fun, Hoong-Kun, Kargar, Hadi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960077/
https://www.ncbi.nlm.nih.gov/pubmed/21581392
http://dx.doi.org/10.1107/S1600536808038695
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author Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
author_facet Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
author_sort Kia, Reza
collection PubMed
description The title compound, C(14)H(13)ClN(2)O(3)S, features an intra­molecular O—H⋯N hydrogen bond which generates an S(6) ring motif. Inter­molecular N—H⋯O hydrogen bonds and C—H⋯O close contacts link neighbouring mol­ecules forming R (2) (2)(13) ring motifs. In the crystal structure, mol­ecules are further linked by C—H⋯Cl inter­actions, forming one-dimensional extended chains along the c axis. The dihedral angle between the two benzene rings is 86.06 (3)°. The crystal structure is further stabilized by weak inter­molecular π–π inter­actions [inter­planar stacking distance = 3.357 (7) Å].
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spelling pubmed-29600772010-12-30 (E)-N′-(5-Chloro-2-hydroxy­benzyl­idene)-p-toluene­sulfonohydrazide Kia, Reza Fun, Hoong-Kun Kargar, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(13)ClN(2)O(3)S, features an intra­molecular O—H⋯N hydrogen bond which generates an S(6) ring motif. Inter­molecular N—H⋯O hydrogen bonds and C—H⋯O close contacts link neighbouring mol­ecules forming R (2) (2)(13) ring motifs. In the crystal structure, mol­ecules are further linked by C—H⋯Cl inter­actions, forming one-dimensional extended chains along the c axis. The dihedral angle between the two benzene rings is 86.06 (3)°. The crystal structure is further stabilized by weak inter­molecular π–π inter­actions [inter­planar stacking distance = 3.357 (7) Å]. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2960077/ /pubmed/21581392 http://dx.doi.org/10.1107/S1600536808038695 Text en © Kia et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
(E)-N′-(5-Chloro-2-hydroxy­benzyl­idene)-p-toluene­sulfonohydrazide
title (E)-N′-(5-Chloro-2-hydroxy­benzyl­idene)-p-toluene­sulfonohydrazide
title_full (E)-N′-(5-Chloro-2-hydroxy­benzyl­idene)-p-toluene­sulfonohydrazide
title_fullStr (E)-N′-(5-Chloro-2-hydroxy­benzyl­idene)-p-toluene­sulfonohydrazide
title_full_unstemmed (E)-N′-(5-Chloro-2-hydroxy­benzyl­idene)-p-toluene­sulfonohydrazide
title_short (E)-N′-(5-Chloro-2-hydroxy­benzyl­idene)-p-toluene­sulfonohydrazide
title_sort (e)-n′-(5-chloro-2-hydroxy­benzyl­idene)-p-toluene­sulfonohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960077/
https://www.ncbi.nlm.nih.gov/pubmed/21581392
http://dx.doi.org/10.1107/S1600536808038695
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AT funhoongkun en5chloro2hydroxybenzylideneptoluenesulfonohydrazide
AT kargarhadi en5chloro2hydroxybenzylideneptoluenesulfonohydrazide

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