4-(Dimethyl­amino)benzaldehyde 4-ethyl­thio­semicarbazone

The title thio­semicarbazone derivative, C(12)H(18)N(4)S, features intra­molecular N—H⋯N and C—H⋯S hydrogen bonds which generate S(5) ring motifs. The dihedral angle between the benzene ring and the thio­urea unit is 6.30 (6)° indicating planarity in the mol­ecule. Inter­molecular N—H⋯S hydrogen bon...

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Detalles Bibliográficos
Autores principales: Salhin, Abdussalam, Razak, Norfarhah Abdul, Rahman, I. A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960080/
https://www.ncbi.nlm.nih.gov/pubmed/21581327
http://dx.doi.org/10.1107/S1600536808037148
Descripción
Sumario:The title thio­semicarbazone derivative, C(12)H(18)N(4)S, features intra­molecular N—H⋯N and C—H⋯S hydrogen bonds which generate S(5) ring motifs. The dihedral angle between the benzene ring and the thio­urea unit is 6.30 (6)° indicating planarity in the mol­ecule. Inter­molecular N—H⋯S hydrogen bonds generate dimers with an R (2) (2)(8) ring motif. The methyl group of the N-ethyl residue is disordered and was refined with site occupancies of 0.521 (5) and 0.479 (5).

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