4-(Dimethyl­amino)benzaldehyde 4-ethyl­thio­semicarbazone

The title thio­semicarbazone derivative, C(12)H(18)N(4)S, features intra­molecular N—H⋯N and C—H⋯S hydrogen bonds which generate S(5) ring motifs. The dihedral angle between the benzene ring and the thio­urea unit is 6.30 (6)° indicating planarity in the mol­ecule. Inter­molecular N—H⋯S hydrogen bon...

Descripción completa

Detalles Bibliográficos
Autores principales: Salhin, Abdussalam, Razak, Norfarhah Abdul, Rahman, I. A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960080/
https://www.ncbi.nlm.nih.gov/pubmed/21581327
http://dx.doi.org/10.1107/S1600536808037148
_version_ 1782188653619970048
author Salhin, Abdussalam
Razak, Norfarhah Abdul
Rahman, I. A.
author_facet Salhin, Abdussalam
Razak, Norfarhah Abdul
Rahman, I. A.
author_sort Salhin, Abdussalam
collection PubMed
description The title thio­semicarbazone derivative, C(12)H(18)N(4)S, features intra­molecular N—H⋯N and C—H⋯S hydrogen bonds which generate S(5) ring motifs. The dihedral angle between the benzene ring and the thio­urea unit is 6.30 (6)° indicating planarity in the mol­ecule. Inter­molecular N—H⋯S hydrogen bonds generate dimers with an R (2) (2)(8) ring motif. The methyl group of the N-ethyl residue is disordered and was refined with site occupancies of 0.521 (5) and 0.479 (5).
format Text
id pubmed-2960080
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29600802010-12-30 4-(Dimethyl­amino)benzaldehyde 4-ethyl­thio­semicarbazone Salhin, Abdussalam Razak, Norfarhah Abdul Rahman, I. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title thio­semicarbazone derivative, C(12)H(18)N(4)S, features intra­molecular N—H⋯N and C—H⋯S hydrogen bonds which generate S(5) ring motifs. The dihedral angle between the benzene ring and the thio­urea unit is 6.30 (6)° indicating planarity in the mol­ecule. Inter­molecular N—H⋯S hydrogen bonds generate dimers with an R (2) (2)(8) ring motif. The methyl group of the N-ethyl residue is disordered and was refined with site occupancies of 0.521 (5) and 0.479 (5). International Union of Crystallography 2008-11-13 /pmc/articles/PMC2960080/ /pubmed/21581327 http://dx.doi.org/10.1107/S1600536808037148 Text en © Salhin et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Salhin, Abdussalam
Razak, Norfarhah Abdul
Rahman, I. A.
4-(Dimethyl­amino)benzaldehyde 4-ethyl­thio­semicarbazone
title 4-(Dimethyl­amino)benzaldehyde 4-ethyl­thio­semicarbazone
title_full 4-(Dimethyl­amino)benzaldehyde 4-ethyl­thio­semicarbazone
title_fullStr 4-(Dimethyl­amino)benzaldehyde 4-ethyl­thio­semicarbazone
title_full_unstemmed 4-(Dimethyl­amino)benzaldehyde 4-ethyl­thio­semicarbazone
title_short 4-(Dimethyl­amino)benzaldehyde 4-ethyl­thio­semicarbazone
title_sort 4-(dimethyl­amino)benzaldehyde 4-ethyl­thio­semicarbazone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960080/
https://www.ncbi.nlm.nih.gov/pubmed/21581327
http://dx.doi.org/10.1107/S1600536808037148
work_keys_str_mv AT salhinabdussalam 4dimethylaminobenzaldehyde4ethylthiosemicarbazone
AT razaknorfarhahabdul 4dimethylaminobenzaldehyde4ethylthiosemicarbazone
AT rahmania 4dimethylaminobenzaldehyde4ethylthiosemicarbazone

Ejemplares similares