Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) dl-tartrate

The reaction of di-2-pyridyl ketone with copper dichloride dihydrate and tartaric acid in water afforded the title compound, [Cu(C(11)H(10)N(2)O(2))(2)]C(4)H(4)O(6). The Cu(II) atom lies on an inversion center N,O,N′-chelated by two di-2-pyridylmethane­diol ligands in a tetragonally distorted octa­h...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhao, Jun, Li, Dong-Sheng, Dong, Wen-Wen, Wang, Dan-Jun, Guo, Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960086/
https://www.ncbi.nlm.nih.gov/pubmed/21581112
http://dx.doi.org/10.1107/S1600536808034983
_version_ 1782188655046033408
author Zhao, Jun
Li, Dong-Sheng
Dong, Wen-Wen
Wang, Dan-Jun
Guo, Li
author_facet Zhao, Jun
Li, Dong-Sheng
Dong, Wen-Wen
Wang, Dan-Jun
Guo, Li
author_sort Zhao, Jun
collection PubMed
description The reaction of di-2-pyridyl ketone with copper dichloride dihydrate and tartaric acid in water afforded the title compound, [Cu(C(11)H(10)N(2)O(2))(2)]C(4)H(4)O(6). The Cu(II) atom lies on an inversion center N,O,N′-chelated by two di-2-pyridylmethane­diol ligands in a tetragonally distorted octa­hedral geometry. The tartrate anion is also located on an inversion center and has disordered hydroxyl groups, each with an occupancy factor of 0.5. The hydroxyl groups of the complex cation are hydrogen bonded to the carboxyl­ate groups of the anion, thus connecting the two building units.
format Text
id pubmed-2960086
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29600862010-12-30 Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) dl-tartrate Zhao, Jun Li, Dong-Sheng Dong, Wen-Wen Wang, Dan-Jun Guo, Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of di-2-pyridyl ketone with copper dichloride dihydrate and tartaric acid in water afforded the title compound, [Cu(C(11)H(10)N(2)O(2))(2)]C(4)H(4)O(6). The Cu(II) atom lies on an inversion center N,O,N′-chelated by two di-2-pyridylmethane­diol ligands in a tetragonally distorted octa­hedral geometry. The tartrate anion is also located on an inversion center and has disordered hydroxyl groups, each with an occupancy factor of 0.5. The hydroxyl groups of the complex cation are hydrogen bonded to the carboxyl­ate groups of the anion, thus connecting the two building units. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2960086/ /pubmed/21581112 http://dx.doi.org/10.1107/S1600536808034983 Text en © Zhao et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Jun
Li, Dong-Sheng
Dong, Wen-Wen
Wang, Dan-Jun
Guo, Li
Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) dl-tartrate
title Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) dl-tartrate
title_full Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) dl-tartrate
title_fullStr Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) dl-tartrate
title_full_unstemmed Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) dl-tartrate
title_short Bis(di-2-pyridylmethane­diol-κ(3) N,O,N′)copper(II) dl-tartrate
title_sort bis(di-2-pyridylmethane­diol-κ(3) n,o,n′)copper(ii) dl-tartrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960086/
https://www.ncbi.nlm.nih.gov/pubmed/21581112
http://dx.doi.org/10.1107/S1600536808034983
work_keys_str_mv AT zhaojun bisdi2pyridylmethanediolk3noncopperiidltartrate
AT lidongsheng bisdi2pyridylmethanediolk3noncopperiidltartrate
AT dongwenwen bisdi2pyridylmethanediolk3noncopperiidltartrate
AT wangdanjun bisdi2pyridylmethanediolk3noncopperiidltartrate
AT guoli bisdi2pyridylmethanediolk3noncopperiidltartrate

Ejemplares similares