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Triaqua(2,2′-bipyridine-κ(2) N,N′)(5-nitroisophthalato-κO (1))zinc(II) monohydrate
In the title compound, [Zn(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Zn(II) cation is hexacoordinated by a chelating 2,2′-bipyridine ligand, one carboxylate O atom from a 5-nitroisophthalate dianion and three water molecules in a slightly distorted octahedral geometry. The structure c...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960092/ https://www.ncbi.nlm.nih.gov/pubmed/21581119 http://dx.doi.org/10.1107/S1600536808035174 |
Sumario: | In the title compound, [Zn(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Zn(II) cation is hexacoordinated by a chelating 2,2′-bipyridine ligand, one carboxylate O atom from a 5-nitroisophthalate dianion and three water molecules in a slightly distorted octahedral geometry. The structure contains isolated neutral complexes, in contrast to coordination polymers formed by Mn(II), Co(II) and Cu(II) with the same ligand set. An extensive network of hydrogen bonds is formed between the water molecules and the carboxylate groups. |
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