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Triaqua­(2,2′-bipyridine-κ(2) N,N′)(5-nitro­isophthalato-κO (1))zinc(II) monohydrate

In the title compound, [Zn(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Zn(II) cation is hexa­coordinated by a chelating 2,2′-bipyridine ligand, one carboxyl­ate O atom from a 5-nitro­isophthalate dianion and three water mol­ecules in a slightly distorted octa­hedral geometry. The structure c...

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Detalles Bibliográficos
Autores principales: Hao, Lujiang, Liu, Xia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960092/
https://www.ncbi.nlm.nih.gov/pubmed/21581119
http://dx.doi.org/10.1107/S1600536808035174
Descripción
Sumario:In the title compound, [Zn(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Zn(II) cation is hexa­coordinated by a chelating 2,2′-bipyridine ligand, one carboxyl­ate O atom from a 5-nitro­isophthalate dianion and three water mol­ecules in a slightly distorted octa­hedral geometry. The structure contains isolated neutral complexes, in contrast to coordination polymers formed by Mn(II), Co(II) and Cu(II) with the same ligand set. An extensive network of hydrogen bonds is formed between the water mol­ecules and the carboxyl­ate groups.