Triaqua­(2,2′-bipyridine-κ(2) N,N′)(5-nitro­isophthalato-κO (1))zinc(II) monohydrate

In the title compound, [Zn(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Zn(II) cation is hexa­coordinated by a chelating 2,2′-bipyridine ligand, one carboxyl­ate O atom from a 5-nitro­isophthalate dianion and three water mol­ecules in a slightly distorted octa­hedral geometry. The structure c...

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Detalles Bibliográficos
Autores principales: Hao, Lujiang, Liu, Xia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960092/
https://www.ncbi.nlm.nih.gov/pubmed/21581119
http://dx.doi.org/10.1107/S1600536808035174
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author Hao, Lujiang
Liu, Xia
author_facet Hao, Lujiang
Liu, Xia
author_sort Hao, Lujiang
collection PubMed
description In the title compound, [Zn(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Zn(II) cation is hexa­coordinated by a chelating 2,2′-bipyridine ligand, one carboxyl­ate O atom from a 5-nitro­isophthalate dianion and three water mol­ecules in a slightly distorted octa­hedral geometry. The structure contains isolated neutral complexes, in contrast to coordination polymers formed by Mn(II), Co(II) and Cu(II) with the same ligand set. An extensive network of hydrogen bonds is formed between the water mol­ecules and the carboxyl­ate groups.
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spelling pubmed-29600922010-12-30 Triaqua­(2,2′-bipyridine-κ(2) N,N′)(5-nitro­isophthalato-κO (1))zinc(II) monohydrate Hao, Lujiang Liu, Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]·H(2)O, the Zn(II) cation is hexa­coordinated by a chelating 2,2′-bipyridine ligand, one carboxyl­ate O atom from a 5-nitro­isophthalate dianion and three water mol­ecules in a slightly distorted octa­hedral geometry. The structure contains isolated neutral complexes, in contrast to coordination polymers formed by Mn(II), Co(II) and Cu(II) with the same ligand set. An extensive network of hydrogen bonds is formed between the water mol­ecules and the carboxyl­ate groups. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2960092/ /pubmed/21581119 http://dx.doi.org/10.1107/S1600536808035174 Text en © Hao and Liu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hao, Lujiang
Liu, Xia
Triaqua­(2,2′-bipyridine-κ(2) N,N′)(5-nitro­isophthalato-κO (1))zinc(II) monohydrate
title Triaqua­(2,2′-bipyridine-κ(2) N,N′)(5-nitro­isophthalato-κO (1))zinc(II) monohydrate
title_full Triaqua­(2,2′-bipyridine-κ(2) N,N′)(5-nitro­isophthalato-κO (1))zinc(II) monohydrate
title_fullStr Triaqua­(2,2′-bipyridine-κ(2) N,N′)(5-nitro­isophthalato-κO (1))zinc(II) monohydrate
title_full_unstemmed Triaqua­(2,2′-bipyridine-κ(2) N,N′)(5-nitro­isophthalato-κO (1))zinc(II) monohydrate
title_short Triaqua­(2,2′-bipyridine-κ(2) N,N′)(5-nitro­isophthalato-κO (1))zinc(II) monohydrate
title_sort triaqua­(2,2′-bipyridine-κ(2) n,n′)(5-nitro­isophthalato-κo (1))zinc(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960092/
https://www.ncbi.nlm.nih.gov/pubmed/21581119
http://dx.doi.org/10.1107/S1600536808035174
work_keys_str_mv AT haolujiang triaqua22bipyridinek2nn5nitroisophthalatoko1zinciimonohydrate
AT liuxia triaqua22bipyridinek2nn5nitroisophthalatoko1zinciimonohydrate

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