Azido­(1,1-diphenyl­methanimine-κN)[hydridotris(pyrazolyl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) diethyl ether solvate

The reaction of [RuCl(C(9)H(10)BN(6))(C(18)H(15)P)(2)] with benzo­phenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(N(3))(HN=CPh(2))(C(18)H(15)P)]·C(4)H(10)O, which crystallizes as the diethyl ether solvate. In the crystal s...

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Detalles Bibliográficos
Autores principales: Lin, Chia-Her, Kuo, Ting-Shen, Tong, Hung-Chun, Chen Hsu, Chih-Yung, Lo, Yih-Hsing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960095/
https://www.ncbi.nlm.nih.gov/pubmed/21581130
http://dx.doi.org/10.1107/S1600536808036039
Descripción
Sumario:The reaction of [RuCl(C(9)H(10)BN(6))(C(18)H(15)P)(2)] with benzo­phenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(N(3))(HN=CPh(2))(C(18)H(15)P)]·C(4)H(10)O, which crystallizes as the diethyl ether solvate. In the crystal structure, the Ru atom is coordinated by three N atoms of one hydridotris(pyrazoly)borate anion, one P atom of one triphenyl­phosphine ligand, one N atom of the azide anion and one N atom of the benzophenone­imine ligand in a slightly distorted octa­hedral geometry. The azide anion is almost linear [177.0 (5)°], with an Ru—N—N angle of 125.9 (3)°. There is a small difference between the N—N distances [1.200 (5) and 1.164 (5) Å], the longer bond being adjacent to the Ru atom.

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