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Azido(1,1-diphenylmethanimine-κN)[hydridotris(pyrazolyl-κN (2))borato](triphenylphosphine-κP)ruthenium(II) diethyl ether solvate
The reaction of [RuCl(C(9)H(10)BN(6))(C(18)H(15)P)(2)] with benzophenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(N(3))(HN=CPh(2))(C(18)H(15)P)]·C(4)H(10)O, which crystallizes as the diethyl ether solvate. In the crystal s...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960095/ https://www.ncbi.nlm.nih.gov/pubmed/21581130 http://dx.doi.org/10.1107/S1600536808036039 |
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author | Lin, Chia-Her Kuo, Ting-Shen Tong, Hung-Chun Chen Hsu, Chih-Yung Lo, Yih-Hsing |
author_facet | Lin, Chia-Her Kuo, Ting-Shen Tong, Hung-Chun Chen Hsu, Chih-Yung Lo, Yih-Hsing |
author_sort | Lin, Chia-Her |
collection | PubMed |
description | The reaction of [RuCl(C(9)H(10)BN(6))(C(18)H(15)P)(2)] with benzophenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(N(3))(HN=CPh(2))(C(18)H(15)P)]·C(4)H(10)O, which crystallizes as the diethyl ether solvate. In the crystal structure, the Ru atom is coordinated by three N atoms of one hydridotris(pyrazoly)borate anion, one P atom of one triphenylphosphine ligand, one N atom of the azide anion and one N atom of the benzophenoneimine ligand in a slightly distorted octahedral geometry. The azide anion is almost linear [177.0 (5)°], with an Ru—N—N angle of 125.9 (3)°. There is a small difference between the N—N distances [1.200 (5) and 1.164 (5) Å], the longer bond being adjacent to the Ru atom. |
format | Text |
id | pubmed-2960095 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29600952010-12-30 Azido(1,1-diphenylmethanimine-κN)[hydridotris(pyrazolyl-κN (2))borato](triphenylphosphine-κP)ruthenium(II) diethyl ether solvate Lin, Chia-Her Kuo, Ting-Shen Tong, Hung-Chun Chen Hsu, Chih-Yung Lo, Yih-Hsing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of [RuCl(C(9)H(10)BN(6))(C(18)H(15)P)(2)] with benzophenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(N(3))(HN=CPh(2))(C(18)H(15)P)]·C(4)H(10)O, which crystallizes as the diethyl ether solvate. In the crystal structure, the Ru atom is coordinated by three N atoms of one hydridotris(pyrazoly)borate anion, one P atom of one triphenylphosphine ligand, one N atom of the azide anion and one N atom of the benzophenoneimine ligand in a slightly distorted octahedral geometry. The azide anion is almost linear [177.0 (5)°], with an Ru—N—N angle of 125.9 (3)°. There is a small difference between the N—N distances [1.200 (5) and 1.164 (5) Å], the longer bond being adjacent to the Ru atom. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2960095/ /pubmed/21581130 http://dx.doi.org/10.1107/S1600536808036039 Text en © Lin et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lin, Chia-Her Kuo, Ting-Shen Tong, Hung-Chun Chen Hsu, Chih-Yung Lo, Yih-Hsing Azido(1,1-diphenylmethanimine-κN)[hydridotris(pyrazolyl-κN (2))borato](triphenylphosphine-κP)ruthenium(II) diethyl ether solvate |
title | Azido(1,1-diphenylmethanimine-κN)[hydridotris(pyrazolyl-κN
(2))borato](triphenylphosphine-κP)ruthenium(II) diethyl ether solvate |
title_full | Azido(1,1-diphenylmethanimine-κN)[hydridotris(pyrazolyl-κN
(2))borato](triphenylphosphine-κP)ruthenium(II) diethyl ether solvate |
title_fullStr | Azido(1,1-diphenylmethanimine-κN)[hydridotris(pyrazolyl-κN
(2))borato](triphenylphosphine-κP)ruthenium(II) diethyl ether solvate |
title_full_unstemmed | Azido(1,1-diphenylmethanimine-κN)[hydridotris(pyrazolyl-κN
(2))borato](triphenylphosphine-κP)ruthenium(II) diethyl ether solvate |
title_short | Azido(1,1-diphenylmethanimine-κN)[hydridotris(pyrazolyl-κN
(2))borato](triphenylphosphine-κP)ruthenium(II) diethyl ether solvate |
title_sort | azido(1,1-diphenylmethanimine-κn)[hydridotris(pyrazolyl-κn
(2))borato](triphenylphosphine-κp)ruthenium(ii) diethyl ether solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960095/ https://www.ncbi.nlm.nih.gov/pubmed/21581130 http://dx.doi.org/10.1107/S1600536808036039 |
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