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Azido­(1,1-diphenyl­methanimine-κN)[hydridotris(pyrazolyl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) diethyl ether solvate

The reaction of [RuCl(C(9)H(10)BN(6))(C(18)H(15)P)(2)] with benzo­phenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(N(3))(HN=CPh(2))(C(18)H(15)P)]·C(4)H(10)O, which crystallizes as the diethyl ether solvate. In the crystal s...

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Autores principales: Lin, Chia-Her, Kuo, Ting-Shen, Tong, Hung-Chun, Chen Hsu, Chih-Yung, Lo, Yih-Hsing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960095/
https://www.ncbi.nlm.nih.gov/pubmed/21581130
http://dx.doi.org/10.1107/S1600536808036039
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author Lin, Chia-Her
Kuo, Ting-Shen
Tong, Hung-Chun
Chen Hsu, Chih-Yung
Lo, Yih-Hsing
author_facet Lin, Chia-Her
Kuo, Ting-Shen
Tong, Hung-Chun
Chen Hsu, Chih-Yung
Lo, Yih-Hsing
author_sort Lin, Chia-Her
collection PubMed
description The reaction of [RuCl(C(9)H(10)BN(6))(C(18)H(15)P)(2)] with benzo­phenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(N(3))(HN=CPh(2))(C(18)H(15)P)]·C(4)H(10)O, which crystallizes as the diethyl ether solvate. In the crystal structure, the Ru atom is coordinated by three N atoms of one hydridotris(pyrazoly)borate anion, one P atom of one triphenyl­phosphine ligand, one N atom of the azide anion and one N atom of the benzophenone­imine ligand in a slightly distorted octa­hedral geometry. The azide anion is almost linear [177.0 (5)°], with an Ru—N—N angle of 125.9 (3)°. There is a small difference between the N—N distances [1.200 (5) and 1.164 (5) Å], the longer bond being adjacent to the Ru atom.
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spelling pubmed-29600952010-12-30 Azido­(1,1-diphenyl­methanimine-κN)[hydridotris(pyrazolyl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) diethyl ether solvate Lin, Chia-Her Kuo, Ting-Shen Tong, Hung-Chun Chen Hsu, Chih-Yung Lo, Yih-Hsing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of [RuCl(C(9)H(10)BN(6))(C(18)H(15)P)(2)] with benzo­phenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(N(3))(HN=CPh(2))(C(18)H(15)P)]·C(4)H(10)O, which crystallizes as the diethyl ether solvate. In the crystal structure, the Ru atom is coordinated by three N atoms of one hydridotris(pyrazoly)borate anion, one P atom of one triphenyl­phosphine ligand, one N atom of the azide anion and one N atom of the benzophenone­imine ligand in a slightly distorted octa­hedral geometry. The azide anion is almost linear [177.0 (5)°], with an Ru—N—N angle of 125.9 (3)°. There is a small difference between the N—N distances [1.200 (5) and 1.164 (5) Å], the longer bond being adjacent to the Ru atom. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2960095/ /pubmed/21581130 http://dx.doi.org/10.1107/S1600536808036039 Text en © Lin et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lin, Chia-Her
Kuo, Ting-Shen
Tong, Hung-Chun
Chen Hsu, Chih-Yung
Lo, Yih-Hsing
Azido­(1,1-diphenyl­methanimine-κN)[hydridotris(pyrazolyl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) diethyl ether solvate
title Azido­(1,1-diphenyl­methanimine-κN)[hydridotris(pyrazolyl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) diethyl ether solvate
title_full Azido­(1,1-diphenyl­methanimine-κN)[hydridotris(pyrazolyl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) diethyl ether solvate
title_fullStr Azido­(1,1-diphenyl­methanimine-κN)[hydridotris(pyrazolyl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) diethyl ether solvate
title_full_unstemmed Azido­(1,1-diphenyl­methanimine-κN)[hydridotris(pyrazolyl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) diethyl ether solvate
title_short Azido­(1,1-diphenyl­methanimine-κN)[hydridotris(pyrazolyl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) diethyl ether solvate
title_sort azido­(1,1-diphenyl­methanimine-κn)[hydridotris(pyrazolyl-κn (2))borato](triphenyl­phosphine-κp)ruthenium(ii) diethyl ether solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960095/
https://www.ncbi.nlm.nih.gov/pubmed/21581130
http://dx.doi.org/10.1107/S1600536808036039
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