Oxonium ammonio­(cyclo­prop­yl)methyl­enebis(hydrogenphospho­nate) monohydrate

The title compound, H(3)O(+)·C(4)H(10)NO(6)P(2) (−)·H(2)O, was obtained from the reaction of cyclo­propane­carbonitrile with PCl(3), followed by dropwise addition of water. The asymmetric unit comprises an oxonium cation, a zwitterionic monoanion containing a positively charged ammonium group and tw...

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Detalles Bibliográficos
Autores principales: Bon, V. V., Dudko, A. V., Kozachkova, A. N., Pekhnyo, V. I.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960100/
https://www.ncbi.nlm.nih.gov/pubmed/21581319
http://dx.doi.org/10.1107/S1600536808037094
Descripción
Sumario:The title compound, H(3)O(+)·C(4)H(10)NO(6)P(2) (−)·H(2)O, was obtained from the reaction of cyclo­propane­carbonitrile with PCl(3), followed by dropwise addition of water. The asymmetric unit comprises an oxonium cation, a zwitterionic monoanion containing a positively charged ammonium group and two negatively charged phospho­nic acid residues and a water mol­ecule of crystallization. The hydroxonium cation and water mol­ecule are hydrogen bonded to the anion and further N—H⋯O and O—H⋯O bonds create a three-dimensional network.

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