Oxonium ammonio­(cyclo­prop­yl)methyl­enebis(hydrogenphospho­nate) monohydrate

The title compound, H(3)O(+)·C(4)H(10)NO(6)P(2) (−)·H(2)O, was obtained from the reaction of cyclo­propane­carbonitrile with PCl(3), followed by dropwise addition of water. The asymmetric unit comprises an oxonium cation, a zwitterionic monoanion containing a positively charged ammonium group and tw...

Descripción completa

Detalles Bibliográficos
Autores principales: Bon, V. V., Dudko, A. V., Kozachkova, A. N., Pekhnyo, V. I.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960100/
https://www.ncbi.nlm.nih.gov/pubmed/21581319
http://dx.doi.org/10.1107/S1600536808037094
_version_ 1782188658312347648
author Bon, V. V.
Dudko, A. V.
Kozachkova, A. N.
Pekhnyo, V. I.
author_facet Bon, V. V.
Dudko, A. V.
Kozachkova, A. N.
Pekhnyo, V. I.
author_sort Bon, V. V.
collection PubMed
description The title compound, H(3)O(+)·C(4)H(10)NO(6)P(2) (−)·H(2)O, was obtained from the reaction of cyclo­propane­carbonitrile with PCl(3), followed by dropwise addition of water. The asymmetric unit comprises an oxonium cation, a zwitterionic monoanion containing a positively charged ammonium group and two negatively charged phospho­nic acid residues and a water mol­ecule of crystallization. The hydroxonium cation and water mol­ecule are hydrogen bonded to the anion and further N—H⋯O and O—H⋯O bonds create a three-dimensional network.
format Text
id pubmed-2960100
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29601002010-12-30 Oxonium ammonio­(cyclo­prop­yl)methyl­enebis(hydrogenphospho­nate) monohydrate Bon, V. V. Dudko, A. V. Kozachkova, A. N. Pekhnyo, V. I. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, H(3)O(+)·C(4)H(10)NO(6)P(2) (−)·H(2)O, was obtained from the reaction of cyclo­propane­carbonitrile with PCl(3), followed by dropwise addition of water. The asymmetric unit comprises an oxonium cation, a zwitterionic monoanion containing a positively charged ammonium group and two negatively charged phospho­nic acid residues and a water mol­ecule of crystallization. The hydroxonium cation and water mol­ecule are hydrogen bonded to the anion and further N—H⋯O and O—H⋯O bonds create a three-dimensional network. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2960100/ /pubmed/21581319 http://dx.doi.org/10.1107/S1600536808037094 Text en © Bon et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bon, V. V.
Dudko, A. V.
Kozachkova, A. N.
Pekhnyo, V. I.
Oxonium ammonio­(cyclo­prop­yl)methyl­enebis(hydrogenphospho­nate) monohydrate
title Oxonium ammonio­(cyclo­prop­yl)methyl­enebis(hydrogenphospho­nate) monohydrate
title_full Oxonium ammonio­(cyclo­prop­yl)methyl­enebis(hydrogenphospho­nate) monohydrate
title_fullStr Oxonium ammonio­(cyclo­prop­yl)methyl­enebis(hydrogenphospho­nate) monohydrate
title_full_unstemmed Oxonium ammonio­(cyclo­prop­yl)methyl­enebis(hydrogenphospho­nate) monohydrate
title_short Oxonium ammonio­(cyclo­prop­yl)methyl­enebis(hydrogenphospho­nate) monohydrate
title_sort oxonium ammonio­(cyclo­prop­yl)methyl­enebis(hydrogenphospho­nate) monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960100/
https://www.ncbi.nlm.nih.gov/pubmed/21581319
http://dx.doi.org/10.1107/S1600536808037094
work_keys_str_mv AT bonvv oxoniumammoniocyclopropylmethylenebishydrogenphosphonatemonohydrate
AT dudkoav oxoniumammoniocyclopropylmethylenebishydrogenphosphonatemonohydrate
AT kozachkovaan oxoniumammoniocyclopropylmethylenebishydrogenphosphonatemonohydrate
AT pekhnyovi oxoniumammoniocyclopropylmethylenebishydrogenphosphonatemonohydrate

Ejemplares similares