Sodium 2-iodo­benzene­sulfonate monohydrate

In the title compound, Na(+)·C(6)H(4)IO(3)S(−)·H(2)O, the Na atom is hexa­coordinated by O atoms, forming a two-dimensional sheet-like structure in the bc plane, with the iodo­benzene rings protruding above and below. Na⋯O contact distances are in the range 2.419 (2)–2.7218 (18) Å and O⋯Na⋯O angles...

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Detalles Bibliográficos
Autores principales: Arshad, Muhammad Nadeem, Tahir, M. Nawaz, Khan, Islam Ullah, Shafiq, Muhammad, Siddiqui, Waseeq Ahmad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960107/
https://www.ncbi.nlm.nih.gov/pubmed/21581218
http://dx.doi.org/10.1107/S1600536808039202
Descripción
Sumario:In the title compound, Na(+)·C(6)H(4)IO(3)S(−)·H(2)O, the Na atom is hexa­coordinated by O atoms, forming a two-dimensional sheet-like structure in the bc plane, with the iodo­benzene rings protruding above and below. Na⋯O contact distances are in the range 2.419 (2)–2.7218 (18) Å and O⋯Na⋯O angles are in the range 73.70 (5)–158.64 (7)°. The crystal structure is stabilized by O—H⋯O and C—H⋯O hydrogen bonds and C—H⋯π inter­actions. The I atom is disordered over two positions with occupancies of 0.78 (2) and 0.22 (2).

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