Cargando…

catena-Poly[[bis­(μ(2)-4-amino­benzene­sulfonato-κ(2) O:O)disilver]-bis­(μ(2)-4,4′-bipyridine-κ(2) N:N′)]

In the title compound, [Ag(2)(C(6)H(6)NO(3)S)(2)(C(10)H(8)N(2))(2)](n), the Ag(I) atom is four-coordinated by two N atoms from two symmetry-related 4,4′-bipyridine (bipy) and two O atoms from two independent 4-amino­benzene­sulfonate (ABS) ligands. The two inter-chain Ag(I) atoms are bridged by two...

Descripción completa

Detalles Bibliográficos
Autores principales: Ou, Guang-Chuan, Zhang, Min, Yuan, Xian-You, Dai, Yong-Qiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960111/
https://www.ncbi.nlm.nih.gov/pubmed/21581187
http://dx.doi.org/10.1107/S160053680803804X
_version_ 1782188660864581632
author Ou, Guang-Chuan
Zhang, Min
Yuan, Xian-You
Dai, Yong-Qiang
author_facet Ou, Guang-Chuan
Zhang, Min
Yuan, Xian-You
Dai, Yong-Qiang
author_sort Ou, Guang-Chuan
collection PubMed
description In the title compound, [Ag(2)(C(6)H(6)NO(3)S)(2)(C(10)H(8)N(2))(2)](n), the Ag(I) atom is four-coordinated by two N atoms from two symmetry-related 4,4′-bipyridine (bipy) and two O atoms from two independent 4-amino­benzene­sulfonate (ABS) ligands. The two inter-chain Ag(I) atoms are bridged by two independent ABS ligands through weak Ag—O bonds and Ag⋯Ag attractions, forming a ladder-like chain coordination polymer [Ag(2)(ABS)(2)(bipy)(2)](n) parallel to [001], which is further linked to generate a two-dimensional structure via N—H⋯O hydrogen-bonding inter­actions.
format Text
id pubmed-2960111
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29601112010-12-30 catena-Poly[[bis­(μ(2)-4-amino­benzene­sulfonato-κ(2) O:O)disilver]-bis­(μ(2)-4,4′-bipyridine-κ(2) N:N′)] Ou, Guang-Chuan Zhang, Min Yuan, Xian-You Dai, Yong-Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(2)(C(6)H(6)NO(3)S)(2)(C(10)H(8)N(2))(2)](n), the Ag(I) atom is four-coordinated by two N atoms from two symmetry-related 4,4′-bipyridine (bipy) and two O atoms from two independent 4-amino­benzene­sulfonate (ABS) ligands. The two inter-chain Ag(I) atoms are bridged by two independent ABS ligands through weak Ag—O bonds and Ag⋯Ag attractions, forming a ladder-like chain coordination polymer [Ag(2)(ABS)(2)(bipy)(2)](n) parallel to [001], which is further linked to generate a two-dimensional structure via N—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2960111/ /pubmed/21581187 http://dx.doi.org/10.1107/S160053680803804X Text en © Ou et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ou, Guang-Chuan
Zhang, Min
Yuan, Xian-You
Dai, Yong-Qiang
catena-Poly[[bis­(μ(2)-4-amino­benzene­sulfonato-κ(2) O:O)disilver]-bis­(μ(2)-4,4′-bipyridine-κ(2) N:N′)]
title catena-Poly[[bis­(μ(2)-4-amino­benzene­sulfonato-κ(2) O:O)disilver]-bis­(μ(2)-4,4′-bipyridine-κ(2) N:N′)]
title_full catena-Poly[[bis­(μ(2)-4-amino­benzene­sulfonato-κ(2) O:O)disilver]-bis­(μ(2)-4,4′-bipyridine-κ(2) N:N′)]
title_fullStr catena-Poly[[bis­(μ(2)-4-amino­benzene­sulfonato-κ(2) O:O)disilver]-bis­(μ(2)-4,4′-bipyridine-κ(2) N:N′)]
title_full_unstemmed catena-Poly[[bis­(μ(2)-4-amino­benzene­sulfonato-κ(2) O:O)disilver]-bis­(μ(2)-4,4′-bipyridine-κ(2) N:N′)]
title_short catena-Poly[[bis­(μ(2)-4-amino­benzene­sulfonato-κ(2) O:O)disilver]-bis­(μ(2)-4,4′-bipyridine-κ(2) N:N′)]
title_sort catena-poly[[bis­(μ(2)-4-amino­benzene­sulfonato-κ(2) o:o)disilver]-bis­(μ(2)-4,4′-bipyridine-κ(2) n:n′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960111/
https://www.ncbi.nlm.nih.gov/pubmed/21581187
http://dx.doi.org/10.1107/S160053680803804X
work_keys_str_mv AT ouguangchuan catenapolybism24aminobenzenesulfonatok2oodisilverbism244bipyridinek2nn
AT zhangmin catenapolybism24aminobenzenesulfonatok2oodisilverbism244bipyridinek2nn
AT yuanxianyou catenapolybism24aminobenzenesulfonatok2oodisilverbism244bipyridinek2nn
AT daiyongqiang catenapolybism24aminobenzenesulfonatok2oodisilverbism244bipyridinek2nn