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(Dithiobenzoato-κ(2) S,S′)[hydridotris(pyrazol-1-yl-κN (2))borato](triphenylphosphine-κP)ruthenium(II)
Reaction of [Ru(Tp)Cl(PPh(3))(2)] (Tp = hydridotrispyrazolylborate) with ammonium dithiobenzoate in methanol leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(C(7)H(5)S(2))(C(18)H(15)P)]. In the crystal structure, the Ru atom is coordinated by three N atoms of the Tp ligand, one P...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960112/ https://www.ncbi.nlm.nih.gov/pubmed/21581150 http://dx.doi.org/10.1107/S1600536808036702 |
| _version_ | 1782188661094219776 |
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| author | Lin, Chia-Her Liang, Yao-Ren Tong, Hung-Chun Lo, Yih Hsing Kuo, Ting Shen |
| author_facet | Lin, Chia-Her Liang, Yao-Ren Tong, Hung-Chun Lo, Yih Hsing Kuo, Ting Shen |
| author_sort | Lin, Chia-Her |
| collection | PubMed |
| description | Reaction of [Ru(Tp)Cl(PPh(3))(2)] (Tp = hydridotrispyrazolylborate) with ammonium dithiobenzoate in methanol leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(C(7)H(5)S(2))(C(18)H(15)P)]. In the crystal structure, the Ru atom is coordinated by three N atoms of the Tp ligand, one P atom of the triphenylphosphine ligand and the two S atoms of the dithiobenzoate ligand within a slightly distorted octahedron. The Ru—S bonds are slightly different [2.321 (1) and 2.396 (1) Å] and the average N—Ru—N angle is 86.31°. |
| format | Text |
| id | pubmed-2960112 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29601122010-12-30 (Dithiobenzoato-κ(2) S,S′)[hydridotris(pyrazol-1-yl-κN (2))borato](triphenylphosphine-κP)ruthenium(II) Lin, Chia-Her Liang, Yao-Ren Tong, Hung-Chun Lo, Yih Hsing Kuo, Ting Shen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Reaction of [Ru(Tp)Cl(PPh(3))(2)] (Tp = hydridotrispyrazolylborate) with ammonium dithiobenzoate in methanol leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(C(7)H(5)S(2))(C(18)H(15)P)]. In the crystal structure, the Ru atom is coordinated by three N atoms of the Tp ligand, one P atom of the triphenylphosphine ligand and the two S atoms of the dithiobenzoate ligand within a slightly distorted octahedron. The Ru—S bonds are slightly different [2.321 (1) and 2.396 (1) Å] and the average N—Ru—N angle is 86.31°. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2960112/ /pubmed/21581150 http://dx.doi.org/10.1107/S1600536808036702 Text en © Lin et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lin, Chia-Her Liang, Yao-Ren Tong, Hung-Chun Lo, Yih Hsing Kuo, Ting Shen (Dithiobenzoato-κ(2) S,S′)[hydridotris(pyrazol-1-yl-κN (2))borato](triphenylphosphine-κP)ruthenium(II) |
| title | (Dithiobenzoato-κ(2)
S,S′)[hydridotris(pyrazol-1-yl-κN
(2))borato](triphenylphosphine-κP)ruthenium(II) |
| title_full | (Dithiobenzoato-κ(2)
S,S′)[hydridotris(pyrazol-1-yl-κN
(2))borato](triphenylphosphine-κP)ruthenium(II) |
| title_fullStr | (Dithiobenzoato-κ(2)
S,S′)[hydridotris(pyrazol-1-yl-κN
(2))borato](triphenylphosphine-κP)ruthenium(II) |
| title_full_unstemmed | (Dithiobenzoato-κ(2)
S,S′)[hydridotris(pyrazol-1-yl-κN
(2))borato](triphenylphosphine-κP)ruthenium(II) |
| title_short | (Dithiobenzoato-κ(2)
S,S′)[hydridotris(pyrazol-1-yl-κN
(2))borato](triphenylphosphine-κP)ruthenium(II) |
| title_sort | (dithiobenzoato-κ(2)
s,s′)[hydridotris(pyrazol-1-yl-κn
(2))borato](triphenylphosphine-κp)ruthenium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960112/ https://www.ncbi.nlm.nih.gov/pubmed/21581150 http://dx.doi.org/10.1107/S1600536808036702 |
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