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Diaqua-2κ(2) O-bis(μ-1-oxido-2-naphthoato)-1:2κ(3) O (1),O (2):O (2′);2:3κ(3) O (2):O (1),O (2′)-bis(1-oxido-2-naphthoato)-1κ(1) O (2),O (2);3κ(2) O (1),O (2)-hexapyridine-1κ(2) N,2κ(2) N,3κ(2) N-trimanganese(II/III) pyridine disolvate dihydrate
The title complex, [Mn(3)(C(11)H(6)O(3))(4)(C(5)H(5)N)(6)(H(2)O)(2)]·2H(2)O·2C(5)H(5)N, is a trinuclear mixed oxidation state complex of [Image: see text] symmetry. The three Mn atoms are six-coordinated in the shape of distorted octahedra, each coordinated with an O(4)N(2) set of donor atoms, wher...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960114/ https://www.ncbi.nlm.nih.gov/pubmed/21581213 http://dx.doi.org/10.1107/S1600536808038439 |
| _version_ | 1782188661577613312 |
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| author | Yang, Hua Chen, Yuting Li, Dacheng Wang, Daqi |
| author_facet | Yang, Hua Chen, Yuting Li, Dacheng Wang, Daqi |
| author_sort | Yang, Hua |
| collection | PubMed |
| description | The title complex, [Mn(3)(C(11)H(6)O(3))(4)(C(5)H(5)N)(6)(H(2)O)(2)]·2H(2)O·2C(5)H(5)N, is a trinuclear mixed oxidation state complex of [Image: see text] symmetry. The three Mn atoms are six-coordinated in the shape of distorted octahedra, each coordinated with an O(4)N(2) set of donor atoms, where the ligands exhibit mono- and bidentate modes. However, the coordination of the Mn(II) ion located on the inversion centre involves water molecules at two coordination sites, whereas that of the two symmetry-related Mn(III) ions involves an O(4)N(2) set of donor atoms orginating from the organic ligands. Intramolecular C—H⋯π interactions between neighbouring pyridine ligands stabilize this arrangement. A two-dimensional network parallel to (001) is formed by intermolecular O—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-2960114 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29601142010-12-30 Diaqua-2κ(2) O-bis(μ-1-oxido-2-naphthoato)-1:2κ(3) O (1),O (2):O (2′);2:3κ(3) O (2):O (1),O (2′)-bis(1-oxido-2-naphthoato)-1κ(1) O (2),O (2);3κ(2) O (1),O (2)-hexapyridine-1κ(2) N,2κ(2) N,3κ(2) N-trimanganese(II/III) pyridine disolvate dihydrate Yang, Hua Chen, Yuting Li, Dacheng Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Mn(3)(C(11)H(6)O(3))(4)(C(5)H(5)N)(6)(H(2)O)(2)]·2H(2)O·2C(5)H(5)N, is a trinuclear mixed oxidation state complex of [Image: see text] symmetry. The three Mn atoms are six-coordinated in the shape of distorted octahedra, each coordinated with an O(4)N(2) set of donor atoms, where the ligands exhibit mono- and bidentate modes. However, the coordination of the Mn(II) ion located on the inversion centre involves water molecules at two coordination sites, whereas that of the two symmetry-related Mn(III) ions involves an O(4)N(2) set of donor atoms orginating from the organic ligands. Intramolecular C—H⋯π interactions between neighbouring pyridine ligands stabilize this arrangement. A two-dimensional network parallel to (001) is formed by intermolecular O—H⋯O hydrogen bonds. International Union of Crystallography 2008-11-26 /pmc/articles/PMC2960114/ /pubmed/21581213 http://dx.doi.org/10.1107/S1600536808038439 Text en © Yang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Yang, Hua Chen, Yuting Li, Dacheng Wang, Daqi Diaqua-2κ(2) O-bis(μ-1-oxido-2-naphthoato)-1:2κ(3) O (1),O (2):O (2′);2:3κ(3) O (2):O (1),O (2′)-bis(1-oxido-2-naphthoato)-1κ(1) O (2),O (2);3κ(2) O (1),O (2)-hexapyridine-1κ(2) N,2κ(2) N,3κ(2) N-trimanganese(II/III) pyridine disolvate dihydrate |
| title | Diaqua-2κ(2)
O-bis(μ-1-oxido-2-naphthoato)-1:2κ(3)
O
(1),O
(2):O
(2′);2:3κ(3)
O
(2):O
(1),O
(2′)-bis(1-oxido-2-naphthoato)-1κ(1)
O
(2),O
(2);3κ(2)
O
(1),O
(2)-hexapyridine-1κ(2)
N,2κ(2)
N,3κ(2)
N-trimanganese(II/III) pyridine disolvate dihydrate |
| title_full | Diaqua-2κ(2)
O-bis(μ-1-oxido-2-naphthoato)-1:2κ(3)
O
(1),O
(2):O
(2′);2:3κ(3)
O
(2):O
(1),O
(2′)-bis(1-oxido-2-naphthoato)-1κ(1)
O
(2),O
(2);3κ(2)
O
(1),O
(2)-hexapyridine-1κ(2)
N,2κ(2)
N,3κ(2)
N-trimanganese(II/III) pyridine disolvate dihydrate |
| title_fullStr | Diaqua-2κ(2)
O-bis(μ-1-oxido-2-naphthoato)-1:2κ(3)
O
(1),O
(2):O
(2′);2:3κ(3)
O
(2):O
(1),O
(2′)-bis(1-oxido-2-naphthoato)-1κ(1)
O
(2),O
(2);3κ(2)
O
(1),O
(2)-hexapyridine-1κ(2)
N,2κ(2)
N,3κ(2)
N-trimanganese(II/III) pyridine disolvate dihydrate |
| title_full_unstemmed | Diaqua-2κ(2)
O-bis(μ-1-oxido-2-naphthoato)-1:2κ(3)
O
(1),O
(2):O
(2′);2:3κ(3)
O
(2):O
(1),O
(2′)-bis(1-oxido-2-naphthoato)-1κ(1)
O
(2),O
(2);3κ(2)
O
(1),O
(2)-hexapyridine-1κ(2)
N,2κ(2)
N,3κ(2)
N-trimanganese(II/III) pyridine disolvate dihydrate |
| title_short | Diaqua-2κ(2)
O-bis(μ-1-oxido-2-naphthoato)-1:2κ(3)
O
(1),O
(2):O
(2′);2:3κ(3)
O
(2):O
(1),O
(2′)-bis(1-oxido-2-naphthoato)-1κ(1)
O
(2),O
(2);3κ(2)
O
(1),O
(2)-hexapyridine-1κ(2)
N,2κ(2)
N,3κ(2)
N-trimanganese(II/III) pyridine disolvate dihydrate |
| title_sort | diaqua-2κ(2)
o-bis(μ-1-oxido-2-naphthoato)-1:2κ(3)
o
(1),o
(2):o
(2′);2:3κ(3)
o
(2):o
(1),o
(2′)-bis(1-oxido-2-naphthoato)-1κ(1)
o
(2),o
(2);3κ(2)
o
(1),o
(2)-hexapyridine-1κ(2)
n,2κ(2)
n,3κ(2)
n-trimanganese(ii/iii) pyridine disolvate dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960114/ https://www.ncbi.nlm.nih.gov/pubmed/21581213 http://dx.doi.org/10.1107/S1600536808038439 |
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