A bi-TTF with a bipyridine spacer: 4,4′-bis­[(3,6,7-trimethyl­sulfanyltetra­thia­fulvalen-2-yl)sulfanylmeth­yl]-2,2′-bipyridine

The title compound, C(30)H(28)N(2)S(16), is a precursor to hybrid magnetic materials. The complete molecule is generated by a crystallographic inversion centre. In the crystal structure, the TTF core is not planar and adopts a chair conformation; the two C(3)S(2) rings are folded around the S⋯S hing...

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Detalles Bibliográficos
Autores principales: Kaboub, Lakhemici, Fabre, Jean-Marc, Legros, Jean-Pierre
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960116/
https://www.ncbi.nlm.nih.gov/pubmed/21581449
http://dx.doi.org/10.1107/S1600536808039111
Descripción
Sumario:The title compound, C(30)H(28)N(2)S(16), is a precursor to hybrid magnetic materials. The complete molecule is generated by a crystallographic inversion centre. In the crystal structure, the TTF core is not planar and adopts a chair conformation; the two C(3)S(2) rings are folded around the S⋯S hinges, the dihedral angles being 17.14 (8) and 13.46 (7)°. There is a short S⋯S contact [3.4863  (14) Å] in the crystal structure.

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