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Tetra­kis(μ-2-anilinobenzoato)bis­[methano­lcopper(II)](Cu—Cu)

The title compound, [Cu(2)(C(13)H(10)NO(2))(4)(CH(4)O)(2)], has been prepared by the reaction of 2-anilinobenzoic acid, HL, with copper(II) nitrate in methanol. This dinuclear complex is arranged around an inversion center. Each Cu atom displays a distorted trigonal–pyramidal coordination with four...

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Detalles Bibliográficos
Autores principales: Xin, Chun-Wei, Liu, Fu-Chen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960117/
https://www.ncbi.nlm.nih.gov/pubmed/21581189
http://dx.doi.org/10.1107/S1600536808038063
Descripción
Sumario:The title compound, [Cu(2)(C(13)H(10)NO(2))(4)(CH(4)O)(2)], has been prepared by the reaction of 2-anilinobenzoic acid, HL, with copper(II) nitrate in methanol. This dinuclear complex is arranged around an inversion center. Each Cu atom displays a distorted trigonal–pyramidal coordination with four O atoms from the four ligands L and one axial O atom of the methanol solvent mol­ecule. Each carboxyl­ate group of the ligands L links two Cu atoms, building a dinuclear complex with a Cu—Cu distance of 2.5774 (10) Å. There are intra­molecular N—H⋯O hydrogen bonds, and the H atom of the methanol mol­ecule is involved in weak bifurcated hydrogen-bonding inter­actions with two carboxyl­ate O atoms of related mol­ecules, forming a chain developing parallel to the a axis.