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Tetrakis(μ-2-anilinobenzoato)bis[methanolcopper(II)](Cu—Cu)
The title compound, [Cu(2)(C(13)H(10)NO(2))(4)(CH(4)O)(2)], has been prepared by the reaction of 2-anilinobenzoic acid, HL, with copper(II) nitrate in methanol. This dinuclear complex is arranged around an inversion center. Each Cu atom displays a distorted trigonal–pyramidal coordination with four...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960117/ https://www.ncbi.nlm.nih.gov/pubmed/21581189 http://dx.doi.org/10.1107/S1600536808038063 |
Sumario: | The title compound, [Cu(2)(C(13)H(10)NO(2))(4)(CH(4)O)(2)], has been prepared by the reaction of 2-anilinobenzoic acid, HL, with copper(II) nitrate in methanol. This dinuclear complex is arranged around an inversion center. Each Cu atom displays a distorted trigonal–pyramidal coordination with four O atoms from the four ligands L and one axial O atom of the methanol solvent molecule. Each carboxylate group of the ligands L links two Cu atoms, building a dinuclear complex with a Cu—Cu distance of 2.5774 (10) Å. There are intramolecular N—H⋯O hydrogen bonds, and the H atom of the methanol molecule is involved in weak bifurcated hydrogen-bonding interactions with two carboxylate O atoms of related molecules, forming a chain developing parallel to the a axis. |
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