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Tetrakis(μ-2-anilinobenzoato)bis[methanolcopper(II)](Cu—Cu)
The title compound, [Cu(2)(C(13)H(10)NO(2))(4)(CH(4)O)(2)], has been prepared by the reaction of 2-anilinobenzoic acid, HL, with copper(II) nitrate in methanol. This dinuclear complex is arranged around an inversion center. Each Cu atom displays a distorted trigonal–pyramidal coordination with four...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960117/ https://www.ncbi.nlm.nih.gov/pubmed/21581189 http://dx.doi.org/10.1107/S1600536808038063 |
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author | Xin, Chun-Wei Liu, Fu-Chen |
author_facet | Xin, Chun-Wei Liu, Fu-Chen |
author_sort | Xin, Chun-Wei |
collection | PubMed |
description | The title compound, [Cu(2)(C(13)H(10)NO(2))(4)(CH(4)O)(2)], has been prepared by the reaction of 2-anilinobenzoic acid, HL, with copper(II) nitrate in methanol. This dinuclear complex is arranged around an inversion center. Each Cu atom displays a distorted trigonal–pyramidal coordination with four O atoms from the four ligands L and one axial O atom of the methanol solvent molecule. Each carboxylate group of the ligands L links two Cu atoms, building a dinuclear complex with a Cu—Cu distance of 2.5774 (10) Å. There are intramolecular N—H⋯O hydrogen bonds, and the H atom of the methanol molecule is involved in weak bifurcated hydrogen-bonding interactions with two carboxylate O atoms of related molecules, forming a chain developing parallel to the a axis. |
format | Text |
id | pubmed-2960117 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29601172010-12-30 Tetrakis(μ-2-anilinobenzoato)bis[methanolcopper(II)](Cu—Cu) Xin, Chun-Wei Liu, Fu-Chen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(13)H(10)NO(2))(4)(CH(4)O)(2)], has been prepared by the reaction of 2-anilinobenzoic acid, HL, with copper(II) nitrate in methanol. This dinuclear complex is arranged around an inversion center. Each Cu atom displays a distorted trigonal–pyramidal coordination with four O atoms from the four ligands L and one axial O atom of the methanol solvent molecule. Each carboxylate group of the ligands L links two Cu atoms, building a dinuclear complex with a Cu—Cu distance of 2.5774 (10) Å. There are intramolecular N—H⋯O hydrogen bonds, and the H atom of the methanol molecule is involved in weak bifurcated hydrogen-bonding interactions with two carboxylate O atoms of related molecules, forming a chain developing parallel to the a axis. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2960117/ /pubmed/21581189 http://dx.doi.org/10.1107/S1600536808038063 Text en © Xin and Liu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xin, Chun-Wei Liu, Fu-Chen Tetrakis(μ-2-anilinobenzoato)bis[methanolcopper(II)](Cu—Cu) |
title | Tetrakis(μ-2-anilinobenzoato)bis[methanolcopper(II)](Cu—Cu) |
title_full | Tetrakis(μ-2-anilinobenzoato)bis[methanolcopper(II)](Cu—Cu) |
title_fullStr | Tetrakis(μ-2-anilinobenzoato)bis[methanolcopper(II)](Cu—Cu) |
title_full_unstemmed | Tetrakis(μ-2-anilinobenzoato)bis[methanolcopper(II)](Cu—Cu) |
title_short | Tetrakis(μ-2-anilinobenzoato)bis[methanolcopper(II)](Cu—Cu) |
title_sort | tetrakis(μ-2-anilinobenzoato)bis[methanolcopper(ii)](cu—cu) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960117/ https://www.ncbi.nlm.nih.gov/pubmed/21581189 http://dx.doi.org/10.1107/S1600536808038063 |
work_keys_str_mv | AT xinchunwei tetrakism2anilinobenzoatobismethanolcopperiicucu AT liufuchen tetrakism2anilinobenzoatobismethanolcopperiicucu |