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Tetra­kis(μ-2-anilinobenzoato)bis­[methano­lcopper(II)](Cu—Cu)

The title compound, [Cu(2)(C(13)H(10)NO(2))(4)(CH(4)O)(2)], has been prepared by the reaction of 2-anilinobenzoic acid, HL, with copper(II) nitrate in methanol. This dinuclear complex is arranged around an inversion center. Each Cu atom displays a distorted trigonal–pyramidal coordination with four...

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Autores principales: Xin, Chun-Wei, Liu, Fu-Chen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960117/
https://www.ncbi.nlm.nih.gov/pubmed/21581189
http://dx.doi.org/10.1107/S1600536808038063
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author Xin, Chun-Wei
Liu, Fu-Chen
author_facet Xin, Chun-Wei
Liu, Fu-Chen
author_sort Xin, Chun-Wei
collection PubMed
description The title compound, [Cu(2)(C(13)H(10)NO(2))(4)(CH(4)O)(2)], has been prepared by the reaction of 2-anilinobenzoic acid, HL, with copper(II) nitrate in methanol. This dinuclear complex is arranged around an inversion center. Each Cu atom displays a distorted trigonal–pyramidal coordination with four O atoms from the four ligands L and one axial O atom of the methanol solvent mol­ecule. Each carboxyl­ate group of the ligands L links two Cu atoms, building a dinuclear complex with a Cu—Cu distance of 2.5774 (10) Å. There are intra­molecular N—H⋯O hydrogen bonds, and the H atom of the methanol mol­ecule is involved in weak bifurcated hydrogen-bonding inter­actions with two carboxyl­ate O atoms of related mol­ecules, forming a chain developing parallel to the a axis.
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spelling pubmed-29601172010-12-30 Tetra­kis(μ-2-anilinobenzoato)bis­[methano­lcopper(II)](Cu—Cu) Xin, Chun-Wei Liu, Fu-Chen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(13)H(10)NO(2))(4)(CH(4)O)(2)], has been prepared by the reaction of 2-anilinobenzoic acid, HL, with copper(II) nitrate in methanol. This dinuclear complex is arranged around an inversion center. Each Cu atom displays a distorted trigonal–pyramidal coordination with four O atoms from the four ligands L and one axial O atom of the methanol solvent mol­ecule. Each carboxyl­ate group of the ligands L links two Cu atoms, building a dinuclear complex with a Cu—Cu distance of 2.5774 (10) Å. There are intra­molecular N—H⋯O hydrogen bonds, and the H atom of the methanol mol­ecule is involved in weak bifurcated hydrogen-bonding inter­actions with two carboxyl­ate O atoms of related mol­ecules, forming a chain developing parallel to the a axis. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2960117/ /pubmed/21581189 http://dx.doi.org/10.1107/S1600536808038063 Text en © Xin and Liu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xin, Chun-Wei
Liu, Fu-Chen
Tetra­kis(μ-2-anilinobenzoato)bis­[methano­lcopper(II)](Cu—Cu)
title Tetra­kis(μ-2-anilinobenzoato)bis­[methano­lcopper(II)](Cu—Cu)
title_full Tetra­kis(μ-2-anilinobenzoato)bis­[methano­lcopper(II)](Cu—Cu)
title_fullStr Tetra­kis(μ-2-anilinobenzoato)bis­[methano­lcopper(II)](Cu—Cu)
title_full_unstemmed Tetra­kis(μ-2-anilinobenzoato)bis­[methano­lcopper(II)](Cu—Cu)
title_short Tetra­kis(μ-2-anilinobenzoato)bis­[methano­lcopper(II)](Cu—Cu)
title_sort tetra­kis(μ-2-anilinobenzoato)bis­[methano­lcopper(ii)](cu—cu)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960117/
https://www.ncbi.nlm.nih.gov/pubmed/21581189
http://dx.doi.org/10.1107/S1600536808038063
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