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Dicarbon­yl[2-hydr­oxy-3,5,7-tris­(mor­pho­linomethyl)cyclo­hepta-2,4,6-trien­onato(1–)-κ(2)O(1),O(2)]rhodium(I)

In the title compound, [Rh(C(22)H(32)N(3)O(5))(CO)(2)], the Rh(I) atom is coordinated by two carbonyl ligands and two tropolonate O atoms in a distorted square-planar geometry. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods. Weak intra­...

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Detalles Bibliográficos
Autores principales: Hill, Tania N., Steyl, G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960118/
https://www.ncbi.nlm.nih.gov/pubmed/21581182
http://dx.doi.org/10.1107/S160053680803780X
Descripción
Sumario:In the title compound, [Rh(C(22)H(32)N(3)O(5))(CO)(2)], the Rh(I) atom is coordinated by two carbonyl ligands and two tropolonate O atoms in a distorted square-planar geometry. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods. Weak intra­molecular C—H⋯N and inter­molecular C—H⋯O hydrogen bonds, and π–π stacking inter­actions between the tropolone rings [centroid–centroid distance = 3.590 (8) Å] are observed in the crystal structure.