Dicarbon­yl[2-hydr­oxy-3,5,7-tris­(mor­pho­linomethyl)cyclo­hepta-2,4,6-trien­onato(1–)-κ(2)O(1),O(2)]rhodium(I)

In the title compound, [Rh(C(22)H(32)N(3)O(5))(CO)(2)], the Rh(I) atom is coordinated by two carbonyl ligands and two tropolonate O atoms in a distorted square-planar geometry. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods. Weak intra­...

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Detalles Bibliográficos
Autores principales: Hill, Tania N., Steyl, G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960118/
https://www.ncbi.nlm.nih.gov/pubmed/21581182
http://dx.doi.org/10.1107/S160053680803780X
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author Hill, Tania N.
Steyl, G.
author_facet Hill, Tania N.
Steyl, G.
author_sort Hill, Tania N.
collection PubMed
description In the title compound, [Rh(C(22)H(32)N(3)O(5))(CO)(2)], the Rh(I) atom is coordinated by two carbonyl ligands and two tropolonate O atoms in a distorted square-planar geometry. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods. Weak intra­molecular C—H⋯N and inter­molecular C—H⋯O hydrogen bonds, and π–π stacking inter­actions between the tropolone rings [centroid–centroid distance = 3.590 (8) Å] are observed in the crystal structure.
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spelling pubmed-29601182010-12-30 Dicarbon­yl[2-hydr­oxy-3,5,7-tris­(mor­pho­linomethyl)cyclo­hepta-2,4,6-trien­onato(1–)-κ(2)O(1),O(2)]rhodium(I) Hill, Tania N. Steyl, G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Rh(C(22)H(32)N(3)O(5))(CO)(2)], the Rh(I) atom is coordinated by two carbonyl ligands and two tropolonate O atoms in a distorted square-planar geometry. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods. Weak intra­molecular C—H⋯N and inter­molecular C—H⋯O hydrogen bonds, and π–π stacking inter­actions between the tropolone rings [centroid–centroid distance = 3.590 (8) Å] are observed in the crystal structure. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2960118/ /pubmed/21581182 http://dx.doi.org/10.1107/S160053680803780X Text en © Hill and Steyl 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hill, Tania N.
Steyl, G.
Dicarbon­yl[2-hydr­oxy-3,5,7-tris­(mor­pho­linomethyl)cyclo­hepta-2,4,6-trien­onato(1–)-κ(2)O(1),O(2)]rhodium(I)
title Dicarbon­yl[2-hydr­oxy-3,5,7-tris­(mor­pho­linomethyl)cyclo­hepta-2,4,6-trien­onato(1–)-κ(2)O(1),O(2)]rhodium(I)
title_full Dicarbon­yl[2-hydr­oxy-3,5,7-tris­(mor­pho­linomethyl)cyclo­hepta-2,4,6-trien­onato(1–)-κ(2)O(1),O(2)]rhodium(I)
title_fullStr Dicarbon­yl[2-hydr­oxy-3,5,7-tris­(mor­pho­linomethyl)cyclo­hepta-2,4,6-trien­onato(1–)-κ(2)O(1),O(2)]rhodium(I)
title_full_unstemmed Dicarbon­yl[2-hydr­oxy-3,5,7-tris­(mor­pho­linomethyl)cyclo­hepta-2,4,6-trien­onato(1–)-κ(2)O(1),O(2)]rhodium(I)
title_short Dicarbon­yl[2-hydr­oxy-3,5,7-tris­(mor­pho­linomethyl)cyclo­hepta-2,4,6-trien­onato(1–)-κ(2)O(1),O(2)]rhodium(I)
title_sort dicarbon­yl[2-hydr­oxy-3,5,7-tris­(mor­pho­linomethyl)cyclo­hepta-2,4,6-trien­onato(1–)-κ(2)o(1),o(2)]rhodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960118/
https://www.ncbi.nlm.nih.gov/pubmed/21581182
http://dx.doi.org/10.1107/S160053680803780X
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AT steylg dicarbonyl2hydroxy357trismorpholinomethylcyclohepta246trienonato1k2o1o2rhodiumi

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