N′-[(Z)-4-Methyl­benzyl­idene]-4-nitro­benzohydrazide monohydrate

In the title compound, C(15)H(13)N(3)O(3)·H(2)O, the two benzene rings form a dihedral angle of 2.03 (2)°. In the crystal structure, adjacent hydrazide mol­ecules are linked into dimers by water mol­ecules; these dimers are then stacked along the b axis. Inter­molecular O—H⋯O, O—H⋯N and C—H⋯O hydrog...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Jebas, Samuel Robinson, Sujith, K. V., Kalluraya, B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960119/
https://www.ncbi.nlm.nih.gov/pubmed/21581313
http://dx.doi.org/10.1107/S1600536808037008
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author Fun, Hoong-Kun
Jebas, Samuel Robinson
Sujith, K. V.
Kalluraya, B.
author_facet Fun, Hoong-Kun
Jebas, Samuel Robinson
Sujith, K. V.
Kalluraya, B.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(15)H(13)N(3)O(3)·H(2)O, the two benzene rings form a dihedral angle of 2.03 (2)°. In the crystal structure, adjacent hydrazide mol­ecules are linked into dimers by water mol­ecules; these dimers are then stacked along the b axis. Inter­molecular O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds and a π–π stacking inter­action between the nitro­benzene and tolyl rings with a centroid–centroid distance of 3.8208 (3) Å are observed. There is also a short O⋯N contact [2.6824 (7) Å].
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spelling pubmed-29601192010-12-30 N′-[(Z)-4-Methyl­benzyl­idene]-4-nitro­benzohydrazide monohydrate Fun, Hoong-Kun Jebas, Samuel Robinson Sujith, K. V. Kalluraya, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(13)N(3)O(3)·H(2)O, the two benzene rings form a dihedral angle of 2.03 (2)°. In the crystal structure, adjacent hydrazide mol­ecules are linked into dimers by water mol­ecules; these dimers are then stacked along the b axis. Inter­molecular O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds and a π–π stacking inter­action between the nitro­benzene and tolyl rings with a centroid–centroid distance of 3.8208 (3) Å are observed. There is also a short O⋯N contact [2.6824 (7) Å]. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2960119/ /pubmed/21581313 http://dx.doi.org/10.1107/S1600536808037008 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Jebas, Samuel Robinson
Sujith, K. V.
Kalluraya, B.
N′-[(Z)-4-Methyl­benzyl­idene]-4-nitro­benzohydrazide monohydrate
title N′-[(Z)-4-Methyl­benzyl­idene]-4-nitro­benzohydrazide monohydrate
title_full N′-[(Z)-4-Methyl­benzyl­idene]-4-nitro­benzohydrazide monohydrate
title_fullStr N′-[(Z)-4-Methyl­benzyl­idene]-4-nitro­benzohydrazide monohydrate
title_full_unstemmed N′-[(Z)-4-Methyl­benzyl­idene]-4-nitro­benzohydrazide monohydrate
title_short N′-[(Z)-4-Methyl­benzyl­idene]-4-nitro­benzohydrazide monohydrate
title_sort n′-[(z)-4-methyl­benzyl­idene]-4-nitro­benzohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960119/
https://www.ncbi.nlm.nih.gov/pubmed/21581313
http://dx.doi.org/10.1107/S1600536808037008
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