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(η(5)-Pentamethylcyclopentadienyl)(η(6)-p-toluenesulfonamide)ruthenium(II) tetraphenylborate
The crystal structure of the title compound, [Ru(C(10)H(15))(C(7)H(9)NO(2)S)]C(24)H(20)B, has been determined as part of our investigation into the structural and biological properties of organometallic Ru(II)–arene–Cp* complex salts of the type [R-PhRuCp*](+)·X (−) (where Cp* is pentamethylcyclo...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960125/ https://www.ncbi.nlm.nih.gov/pubmed/21581173 http://dx.doi.org/10.1107/S1600536808037689 |
| _version_ | 1782188664230510592 |
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| author | Loughrey, Bradley T. Williams, Michael L. Poulsen, Sally-Ann Healy, Peter C. |
| author_facet | Loughrey, Bradley T. Williams, Michael L. Poulsen, Sally-Ann Healy, Peter C. |
| author_sort | Loughrey, Bradley T. |
| collection | PubMed |
| description | The crystal structure of the title compound, [Ru(C(10)H(15))(C(7)H(9)NO(2)S)]C(24)H(20)B, has been determined as part of our investigation into the structural and biological properties of organometallic Ru(II)–arene–Cp* complex salts of the type [R-PhRuCp*](+)·X (−) (where Cp* is pentamethylcyclopentadiene). Tethering the RuCp* group to the benzene ring of p-toluenesulfonamide results in only minor changes to the molecular geometry of the sulfonamide, but, together with crystallization as the [BPh(4)](−) salt, effectively blocks involvement of the sulfonamide group in N—H⋯O hydrogen-bonding networks. |
| format | Text |
| id | pubmed-2960125 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29601252010-12-30 (η(5)-Pentamethylcyclopentadienyl)(η(6)-p-toluenesulfonamide)ruthenium(II) tetraphenylborate Loughrey, Bradley T. Williams, Michael L. Poulsen, Sally-Ann Healy, Peter C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Ru(C(10)H(15))(C(7)H(9)NO(2)S)]C(24)H(20)B, has been determined as part of our investigation into the structural and biological properties of organometallic Ru(II)–arene–Cp* complex salts of the type [R-PhRuCp*](+)·X (−) (where Cp* is pentamethylcyclopentadiene). Tethering the RuCp* group to the benzene ring of p-toluenesulfonamide results in only minor changes to the molecular geometry of the sulfonamide, but, together with crystallization as the [BPh(4)](−) salt, effectively blocks involvement of the sulfonamide group in N—H⋯O hydrogen-bonding networks. International Union of Crystallography 2008-11-20 /pmc/articles/PMC2960125/ /pubmed/21581173 http://dx.doi.org/10.1107/S1600536808037689 Text en © Loughrey et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Loughrey, Bradley T. Williams, Michael L. Poulsen, Sally-Ann Healy, Peter C. (η(5)-Pentamethylcyclopentadienyl)(η(6)-p-toluenesulfonamide)ruthenium(II) tetraphenylborate |
| title | (η(5)-Pentamethylcyclopentadienyl)(η(6)-p-toluenesulfonamide)ruthenium(II) tetraphenylborate |
| title_full | (η(5)-Pentamethylcyclopentadienyl)(η(6)-p-toluenesulfonamide)ruthenium(II) tetraphenylborate |
| title_fullStr | (η(5)-Pentamethylcyclopentadienyl)(η(6)-p-toluenesulfonamide)ruthenium(II) tetraphenylborate |
| title_full_unstemmed | (η(5)-Pentamethylcyclopentadienyl)(η(6)-p-toluenesulfonamide)ruthenium(II) tetraphenylborate |
| title_short | (η(5)-Pentamethylcyclopentadienyl)(η(6)-p-toluenesulfonamide)ruthenium(II) tetraphenylborate |
| title_sort | (η(5)-pentamethylcyclopentadienyl)(η(6)-p-toluenesulfonamide)ruthenium(ii) tetraphenylborate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960125/ https://www.ncbi.nlm.nih.gov/pubmed/21581173 http://dx.doi.org/10.1107/S1600536808037689 |
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