Cargando…

catena-Poly[[aqua­(2,2′-bipyridyl)cobalt(II)]-μ-5-nitro­isophthalato]

In the crystal structure of the title compound, [Co(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)](n), there are two symmetry-independent one-dimensional coordination polymers, which are approximately related by noncrystallographic inversion symmetry. Each zigzag chain is constructed from one Co(II) ion, one...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Ying, He, Qingpeng, Zhang, Xianxi, Xue, Zechun, Lv, Chunyan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960127/
https://www.ncbi.nlm.nih.gov/pubmed/21581202
http://dx.doi.org/10.1107/S1600536808038178
_version_ 1782188664704466944
author Liu, Ying
He, Qingpeng
Zhang, Xianxi
Xue, Zechun
Lv, Chunyan
author_facet Liu, Ying
He, Qingpeng
Zhang, Xianxi
Xue, Zechun
Lv, Chunyan
author_sort Liu, Ying
collection PubMed
description In the crystal structure of the title compound, [Co(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)](n), there are two symmetry-independent one-dimensional coordination polymers, which are approximately related by noncrystallographic inversion symmetry. Each zigzag chain is constructed from one Co(II) ion, one O-monodentate 5-nitro­isophthalate (ndc) dianion, one N,N′-bidentate 2,2′-bipyridyl ligand and one water mol­ecule. A symmetry-generated O,O′-bidentate ndc dianion completes the cobalt coordination environment, which could be described as very distorted cis-CoN(2)O(4) octa­hedral. The bridging ndc ligands result in parallel chains running along the a direction, and O—H⋯O hydrogen bonds arising from the water mol­ecules complete the structure.
format Text
id pubmed-2960127
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29601272010-12-30 catena-Poly[[aqua­(2,2′-bipyridyl)cobalt(II)]-μ-5-nitro­isophthalato] Liu, Ying He, Qingpeng Zhang, Xianxi Xue, Zechun Lv, Chunyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Co(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)](n), there are two symmetry-independent one-dimensional coordination polymers, which are approximately related by noncrystallographic inversion symmetry. Each zigzag chain is constructed from one Co(II) ion, one O-monodentate 5-nitro­isophthalate (ndc) dianion, one N,N′-bidentate 2,2′-bipyridyl ligand and one water mol­ecule. A symmetry-generated O,O′-bidentate ndc dianion completes the cobalt coordination environment, which could be described as very distorted cis-CoN(2)O(4) octa­hedral. The bridging ndc ligands result in parallel chains running along the a direction, and O—H⋯O hydrogen bonds arising from the water mol­ecules complete the structure. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2960127/ /pubmed/21581202 http://dx.doi.org/10.1107/S1600536808038178 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Ying
He, Qingpeng
Zhang, Xianxi
Xue, Zechun
Lv, Chunyan
catena-Poly[[aqua­(2,2′-bipyridyl)cobalt(II)]-μ-5-nitro­isophthalato]
title catena-Poly[[aqua­(2,2′-bipyridyl)cobalt(II)]-μ-5-nitro­isophthalato]
title_full catena-Poly[[aqua­(2,2′-bipyridyl)cobalt(II)]-μ-5-nitro­isophthalato]
title_fullStr catena-Poly[[aqua­(2,2′-bipyridyl)cobalt(II)]-μ-5-nitro­isophthalato]
title_full_unstemmed catena-Poly[[aqua­(2,2′-bipyridyl)cobalt(II)]-μ-5-nitro­isophthalato]
title_short catena-Poly[[aqua­(2,2′-bipyridyl)cobalt(II)]-μ-5-nitro­isophthalato]
title_sort catena-poly[[aqua­(2,2′-bipyridyl)cobalt(ii)]-μ-5-nitro­isophthalato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960127/
https://www.ncbi.nlm.nih.gov/pubmed/21581202
http://dx.doi.org/10.1107/S1600536808038178
work_keys_str_mv AT liuying catenapolyaqua22bipyridylcobaltiim5nitroisophthalato
AT heqingpeng catenapolyaqua22bipyridylcobaltiim5nitroisophthalato
AT zhangxianxi catenapolyaqua22bipyridylcobaltiim5nitroisophthalato
AT xuezechun catenapolyaqua22bipyridylcobaltiim5nitroisophthalato
AT lvchunyan catenapolyaqua22bipyridylcobaltiim5nitroisophthalato