(1R,3S,5R,6S)-6-Acet­oxy-3-(4-methyl­phenyl­sulfon­yloxy)tropane

In the title compound [systematic name: (1R,3S,5R,6S)-8-methyl-3-(4-methyl­phenyl­sulfon­yloxy)-8-aza­bicyclo­[3.2.1]octan-6-yl acetate], C(17)H(23)NO(5)S, the fused piperidine ring exists in a chair conformation with the N atom and one C atom displaced by 0.876 (2) and −0.460 (3) Å, respectively, o...

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Detalles Bibliográficos
Autores principales: Yang, Li-Min, Zhu, Liang, Niu, Yin-Yao, Chen, Hong-Zhuan, Lu, Yang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960129/
https://www.ncbi.nlm.nih.gov/pubmed/21581306
http://dx.doi.org/10.1107/S1600536808035800
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author Yang, Li-Min
Zhu, Liang
Niu, Yin-Yao
Chen, Hong-Zhuan
Lu, Yang
author_facet Yang, Li-Min
Zhu, Liang
Niu, Yin-Yao
Chen, Hong-Zhuan
Lu, Yang
author_sort Yang, Li-Min
collection PubMed
description In the title compound [systematic name: (1R,3S,5R,6S)-8-methyl-3-(4-methyl­phenyl­sulfon­yloxy)-8-aza­bicyclo­[3.2.1]octan-6-yl acetate], C(17)H(23)NO(5)S, the fused piperidine ring exists in a chair conformation with the N atom and one C atom displaced by 0.876 (2) and −0.460 (3) Å, respectively, on opposite sides of the mean plane defined by the other four atoms. The fused pyrrolidine ring adopts an envelope conformation with the N atom deviating by 0.644 (3) Å from the mean plane of the other four atoms.
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spelling pubmed-29601292010-12-30 (1R,3S,5R,6S)-6-Acet­oxy-3-(4-methyl­phenyl­sulfon­yloxy)tropane Yang, Li-Min Zhu, Liang Niu, Yin-Yao Chen, Hong-Zhuan Lu, Yang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound [systematic name: (1R,3S,5R,6S)-8-methyl-3-(4-methyl­phenyl­sulfon­yloxy)-8-aza­bicyclo­[3.2.1]octan-6-yl acetate], C(17)H(23)NO(5)S, the fused piperidine ring exists in a chair conformation with the N atom and one C atom displaced by 0.876 (2) and −0.460 (3) Å, respectively, on opposite sides of the mean plane defined by the other four atoms. The fused pyrrolidine ring adopts an envelope conformation with the N atom deviating by 0.644 (3) Å from the mean plane of the other four atoms. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2960129/ /pubmed/21581306 http://dx.doi.org/10.1107/S1600536808035800 Text en © Yang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yang, Li-Min
Zhu, Liang
Niu, Yin-Yao
Chen, Hong-Zhuan
Lu, Yang
(1R,3S,5R,6S)-6-Acet­oxy-3-(4-methyl­phenyl­sulfon­yloxy)tropane
title (1R,3S,5R,6S)-6-Acet­oxy-3-(4-methyl­phenyl­sulfon­yloxy)tropane
title_full (1R,3S,5R,6S)-6-Acet­oxy-3-(4-methyl­phenyl­sulfon­yloxy)tropane
title_fullStr (1R,3S,5R,6S)-6-Acet­oxy-3-(4-methyl­phenyl­sulfon­yloxy)tropane
title_full_unstemmed (1R,3S,5R,6S)-6-Acet­oxy-3-(4-methyl­phenyl­sulfon­yloxy)tropane
title_short (1R,3S,5R,6S)-6-Acet­oxy-3-(4-methyl­phenyl­sulfon­yloxy)tropane
title_sort (1r,3s,5r,6s)-6-acet­oxy-3-(4-methyl­phenyl­sulfon­yloxy)tropane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960129/
https://www.ncbi.nlm.nih.gov/pubmed/21581306
http://dx.doi.org/10.1107/S1600536808035800
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