Poly[di-μ(3)-chlorido-[μ(2)-(3-pyrid­yl)(4-pyrid­yl)methanone-κ(2) N:N′]dicopper(I)]

In the title compound, [Cu(2)Cl(2)(C(11)H(8)N(2)O)](n), stair-like ribbons of formula [Cu(2)Cl(2)](n) are linked into coordination polymer layers by tethering (3-pyrid­yl)(4-pyrid­yl)methanone (3,4′-dpk) ligands. The two distinct Cu(I) centres both adopt distorted CuNCl(3) tetra­hedral coordinations...

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Detalles Bibliográficos
Autores principales: Hittle, Jennifer L., LaDuca, Robert L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960131/
https://www.ncbi.nlm.nih.gov/pubmed/21581196
http://dx.doi.org/10.1107/S1600536808038385
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author Hittle, Jennifer L.
LaDuca, Robert L.
author_facet Hittle, Jennifer L.
LaDuca, Robert L.
author_sort Hittle, Jennifer L.
collection PubMed
description In the title compound, [Cu(2)Cl(2)(C(11)H(8)N(2)O)](n), stair-like ribbons of formula [Cu(2)Cl(2)](n) are linked into coordination polymer layers by tethering (3-pyrid­yl)(4-pyrid­yl)methanone (3,4′-dpk) ligands. The two distinct Cu(I) centres both adopt distorted CuNCl(3) tetra­hedral coordinations. Individual [Cu(2)Cl(2)(3,4′-dpk)](n) layers stack in an AB pattern along the c direction by way of weak C—H⋯O inter­actions between the pyridyl rings and ketone O atoms.
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spelling pubmed-29601312010-12-30 Poly[di-μ(3)-chlorido-[μ(2)-(3-pyrid­yl)(4-pyrid­yl)methanone-κ(2) N:N′]dicopper(I)] Hittle, Jennifer L. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)Cl(2)(C(11)H(8)N(2)O)](n), stair-like ribbons of formula [Cu(2)Cl(2)](n) are linked into coordination polymer layers by tethering (3-pyrid­yl)(4-pyrid­yl)methanone (3,4′-dpk) ligands. The two distinct Cu(I) centres both adopt distorted CuNCl(3) tetra­hedral coordinations. Individual [Cu(2)Cl(2)(3,4′-dpk)](n) layers stack in an AB pattern along the c direction by way of weak C—H⋯O inter­actions between the pyridyl rings and ketone O atoms. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2960131/ /pubmed/21581196 http://dx.doi.org/10.1107/S1600536808038385 Text en © Hittle and LaDuca 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hittle, Jennifer L.
LaDuca, Robert L.
Poly[di-μ(3)-chlorido-[μ(2)-(3-pyrid­yl)(4-pyrid­yl)methanone-κ(2) N:N′]dicopper(I)]
title Poly[di-μ(3)-chlorido-[μ(2)-(3-pyrid­yl)(4-pyrid­yl)methanone-κ(2) N:N′]dicopper(I)]
title_full Poly[di-μ(3)-chlorido-[μ(2)-(3-pyrid­yl)(4-pyrid­yl)methanone-κ(2) N:N′]dicopper(I)]
title_fullStr Poly[di-μ(3)-chlorido-[μ(2)-(3-pyrid­yl)(4-pyrid­yl)methanone-κ(2) N:N′]dicopper(I)]
title_full_unstemmed Poly[di-μ(3)-chlorido-[μ(2)-(3-pyrid­yl)(4-pyrid­yl)methanone-κ(2) N:N′]dicopper(I)]
title_short Poly[di-μ(3)-chlorido-[μ(2)-(3-pyrid­yl)(4-pyrid­yl)methanone-κ(2) N:N′]dicopper(I)]
title_sort poly[di-μ(3)-chlorido-[μ(2)-(3-pyrid­yl)(4-pyrid­yl)methanone-κ(2) n:n′]dicopper(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960131/
https://www.ncbi.nlm.nih.gov/pubmed/21581196
http://dx.doi.org/10.1107/S1600536808038385
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