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m-Phenylenediamine
In the title compound, C(6)H(8)N(2), there are four molecules in the asymmetric unit, with each molecule, including the H atoms on the N atoms of the amino groups, showing local C2 symmetry. In the crystal structure, all except one of the NH(2) groups participate in N—H⋯O hydrogen bonding. The ide...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960132/ https://www.ncbi.nlm.nih.gov/pubmed/21581461 http://dx.doi.org/10.1107/S1600536808039950 |
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author | Betz, Richard Klüfers, Peter Mayer, Peter |
author_facet | Betz, Richard Klüfers, Peter Mayer, Peter |
author_sort | Betz, Richard |
collection | PubMed |
description | In the title compound, C(6)H(8)N(2), there are four molecules in the asymmetric unit, with each molecule, including the H atoms on the N atoms of the amino groups, showing local C2 symmetry. In the crystal structure, all except one of the NH(2) groups participate in N—H⋯O hydrogen bonding. The identified hydrogen bonds furnish a three-dimensional network. N—H⋯π contacts are observed with H⋯π distances ranging from 2.516 (17) to 2.815 (16) Å. No π-stacking of the aromatic rings is observed. |
format | Text |
id | pubmed-2960132 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29601322010-12-30 m-Phenylenediamine Betz, Richard Klüfers, Peter Mayer, Peter Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(8)N(2), there are four molecules in the asymmetric unit, with each molecule, including the H atoms on the N atoms of the amino groups, showing local C2 symmetry. In the crystal structure, all except one of the NH(2) groups participate in N—H⋯O hydrogen bonding. The identified hydrogen bonds furnish a three-dimensional network. N—H⋯π contacts are observed with H⋯π distances ranging from 2.516 (17) to 2.815 (16) Å. No π-stacking of the aromatic rings is observed. International Union of Crystallography 2008-11-29 /pmc/articles/PMC2960132/ /pubmed/21581461 http://dx.doi.org/10.1107/S1600536808039950 Text en © Betz et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Betz, Richard Klüfers, Peter Mayer, Peter m-Phenylenediamine |
title |
m-Phenylenediamine |
title_full |
m-Phenylenediamine |
title_fullStr |
m-Phenylenediamine |
title_full_unstemmed |
m-Phenylenediamine |
title_short |
m-Phenylenediamine |
title_sort | m-phenylenediamine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960132/ https://www.ncbi.nlm.nih.gov/pubmed/21581461 http://dx.doi.org/10.1107/S1600536808039950 |
work_keys_str_mv | AT betzrichard mphenylenediamine AT kluferspeter mphenylenediamine AT mayerpeter mphenylenediamine |