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m-Phenyl­enediamine

In the title compound, C(6)H(8)N(2), there are four mol­ecules in the asymmetric unit, with each mol­ecule, including the H atoms on the N atoms of the amino groups, showing local C2 symmetry. In the crystal structure, all except one of the NH(2) groups participate in N—H⋯O hydrogen bonding. The ide...

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Detalles Bibliográficos
Autores principales: Betz, Richard, Klüfers, Peter, Mayer, Peter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960132/
https://www.ncbi.nlm.nih.gov/pubmed/21581461
http://dx.doi.org/10.1107/S1600536808039950
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author Betz, Richard
Klüfers, Peter
Mayer, Peter
author_facet Betz, Richard
Klüfers, Peter
Mayer, Peter
author_sort Betz, Richard
collection PubMed
description In the title compound, C(6)H(8)N(2), there are four mol­ecules in the asymmetric unit, with each mol­ecule, including the H atoms on the N atoms of the amino groups, showing local C2 symmetry. In the crystal structure, all except one of the NH(2) groups participate in N—H⋯O hydrogen bonding. The identified hydrogen bonds furnish a three-dimensional network. N—H⋯π contacts are observed with H⋯π distances ranging from 2.516 (17) to 2.815 (16) Å. No π-stacking of the aromatic rings is observed.
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spelling pubmed-29601322010-12-30 m-Phenyl­enediamine Betz, Richard Klüfers, Peter Mayer, Peter Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(8)N(2), there are four mol­ecules in the asymmetric unit, with each mol­ecule, including the H atoms on the N atoms of the amino groups, showing local C2 symmetry. In the crystal structure, all except one of the NH(2) groups participate in N—H⋯O hydrogen bonding. The identified hydrogen bonds furnish a three-dimensional network. N—H⋯π contacts are observed with H⋯π distances ranging from 2.516 (17) to 2.815 (16) Å. No π-stacking of the aromatic rings is observed. International Union of Crystallography 2008-11-29 /pmc/articles/PMC2960132/ /pubmed/21581461 http://dx.doi.org/10.1107/S1600536808039950 Text en © Betz et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Betz, Richard
Klüfers, Peter
Mayer, Peter
m-Phenyl­enediamine
title m-Phenyl­enediamine
title_full m-Phenyl­enediamine
title_fullStr m-Phenyl­enediamine
title_full_unstemmed m-Phenyl­enediamine
title_short m-Phenyl­enediamine
title_sort m-phenyl­enediamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960132/
https://www.ncbi.nlm.nih.gov/pubmed/21581461
http://dx.doi.org/10.1107/S1600536808039950
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