Methyl­ene bis­(dithio­benzoate)

In the title compound, C(15)H(12)S(4), two phenyl­dithio­carboxyl­ate units are linked through a methyl­ene C atom on a twofold rotation axis. The central S—CH(2)—S angle of 116.9 (5)° is significantly larger than the ideal tetra­hedral value. The dihedral angle formed by the two phenyl rings is 68....

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Detalles Bibliográficos
Autores principales: Liang, Yao-Ren, Tong, Hung-Chun, Lo, Yih-Hsing, Lin, Chia-Her, Kuo, Ting Shen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960133/
https://www.ncbi.nlm.nih.gov/pubmed/21581338
http://dx.doi.org/10.1107/S1600536808037379
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author Liang, Yao-Ren
Tong, Hung-Chun
Lo, Yih-Hsing
Lin, Chia-Her
Kuo, Ting Shen
author_facet Liang, Yao-Ren
Tong, Hung-Chun
Lo, Yih-Hsing
Lin, Chia-Her
Kuo, Ting Shen
author_sort Liang, Yao-Ren
collection PubMed
description In the title compound, C(15)H(12)S(4), two phenyl­dithio­carboxyl­ate units are linked through a methyl­ene C atom on a twofold rotation axis. The central S—CH(2)—S angle of 116.9 (5)° is significantly larger than the ideal tetra­hedral value. The dihedral angle formed by the two phenyl rings is 68.2 (1)°. The refined Flack parameter of 0.2 (3) does not permit unambiguous determination of the absolute structure.
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spelling pubmed-29601332010-12-30 Methyl­ene bis­(dithio­benzoate) Liang, Yao-Ren Tong, Hung-Chun Lo, Yih-Hsing Lin, Chia-Her Kuo, Ting Shen Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(12)S(4), two phenyl­dithio­carboxyl­ate units are linked through a methyl­ene C atom on a twofold rotation axis. The central S—CH(2)—S angle of 116.9 (5)° is significantly larger than the ideal tetra­hedral value. The dihedral angle formed by the two phenyl rings is 68.2 (1)°. The refined Flack parameter of 0.2 (3) does not permit unambiguous determination of the absolute structure. International Union of Crystallography 2008-11-13 /pmc/articles/PMC2960133/ /pubmed/21581338 http://dx.doi.org/10.1107/S1600536808037379 Text en © Liang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liang, Yao-Ren
Tong, Hung-Chun
Lo, Yih-Hsing
Lin, Chia-Her
Kuo, Ting Shen
Methyl­ene bis­(dithio­benzoate)
title Methyl­ene bis­(dithio­benzoate)
title_full Methyl­ene bis­(dithio­benzoate)
title_fullStr Methyl­ene bis­(dithio­benzoate)
title_full_unstemmed Methyl­ene bis­(dithio­benzoate)
title_short Methyl­ene bis­(dithio­benzoate)
title_sort methyl­ene bis­(dithio­benzoate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960133/
https://www.ncbi.nlm.nih.gov/pubmed/21581338
http://dx.doi.org/10.1107/S1600536808037379
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AT tonghungchun methylenebisdithiobenzoate
AT loyihhsing methylenebisdithiobenzoate
AT linchiaher methylenebisdithiobenzoate
AT kuotingshen methylenebisdithiobenzoate

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