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A new β-octamolybdate(VI) salt based on 1,4-bis(2-methyl-1H-imidazol-1-yl)butane
The title compound, bis[2,2′-dimethyl-3,3′-(butane-1,4-diyl)diimidazol-1-ium] β-octamolybdate(VI), (C(12)H(20)N(4))(2)[Mo(8)O(26)], was produced by hydrothermal reaction of an acidified aqueous solution of Na(2)MoO(4) and 1,4-bis(2-methyl-1H-imidazol-1-yl)butane (hereafter L). The structure of...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960135/ https://www.ncbi.nlm.nih.gov/pubmed/21581111 http://dx.doi.org/10.1107/S1600536808035022 |
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author | Li, Shun-Li Tan, Ke |
author_facet | Li, Shun-Li Tan, Ke |
author_sort | Li, Shun-Li |
collection | PubMed |
description | The title compound, bis[2,2′-dimethyl-3,3′-(butane-1,4-diyl)diimidazol-1-ium] β-octamolybdate(VI), (C(12)H(20)N(4))(2)[Mo(8)O(26)], was produced by hydrothermal reaction of an acidified aqueous solution of Na(2)MoO(4) and 1,4-bis(2-methyl-1H-imidazol-1-yl)butane (hereafter L). The structure of the title compound consists of the β-octamolybdate anions having a center of symmetry, and protonated [H(2) L](2+) cations, which link the β-octamolybdate anions, generating a supramolecular chain via hydrogen bonds. |
format | Text |
id | pubmed-2960135 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29601352010-12-30 A new β-octamolybdate(VI) salt based on 1,4-bis(2-methyl-1H-imidazol-1-yl)butane Li, Shun-Li Tan, Ke Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, bis[2,2′-dimethyl-3,3′-(butane-1,4-diyl)diimidazol-1-ium] β-octamolybdate(VI), (C(12)H(20)N(4))(2)[Mo(8)O(26)], was produced by hydrothermal reaction of an acidified aqueous solution of Na(2)MoO(4) and 1,4-bis(2-methyl-1H-imidazol-1-yl)butane (hereafter L). The structure of the title compound consists of the β-octamolybdate anions having a center of symmetry, and protonated [H(2) L](2+) cations, which link the β-octamolybdate anions, generating a supramolecular chain via hydrogen bonds. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2960135/ /pubmed/21581111 http://dx.doi.org/10.1107/S1600536808035022 Text en © Li and Tan 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Shun-Li Tan, Ke A new β-octamolybdate(VI) salt based on 1,4-bis(2-methyl-1H-imidazol-1-yl)butane |
title | A new β-octamolybdate(VI) salt based on 1,4-bis(2-methyl-1H-imidazol-1-yl)butane |
title_full | A new β-octamolybdate(VI) salt based on 1,4-bis(2-methyl-1H-imidazol-1-yl)butane |
title_fullStr | A new β-octamolybdate(VI) salt based on 1,4-bis(2-methyl-1H-imidazol-1-yl)butane |
title_full_unstemmed | A new β-octamolybdate(VI) salt based on 1,4-bis(2-methyl-1H-imidazol-1-yl)butane |
title_short | A new β-octamolybdate(VI) salt based on 1,4-bis(2-methyl-1H-imidazol-1-yl)butane |
title_sort | new β-octamolybdate(vi) salt based on 1,4-bis(2-methyl-1h-imidazol-1-yl)butane |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960135/ https://www.ncbi.nlm.nih.gov/pubmed/21581111 http://dx.doi.org/10.1107/S1600536808035022 |
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