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A new β-octa­molybdate(VI) salt based on 1,4-bis­(2-methyl-1H-imidazol-1-yl)butane

The title compound, bis­[2,2′-dimethyl-3,3′-(butane-1,4-di­yl)diimidazol-1-ium] β-octa­molybdate(VI), (C(12)H(20)N(4))(2)[Mo(8)O(26)], was produced by hydro­thermal reaction of an acidified aqueous solution of Na(2)MoO(4) and 1,4-bis­(2-methyl-1H-imidazol-1-yl)butane (hereafter L). The structure of...

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Detalles Bibliográficos
Autores principales: Li, Shun-Li, Tan, Ke
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960135/
https://www.ncbi.nlm.nih.gov/pubmed/21581111
http://dx.doi.org/10.1107/S1600536808035022
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author Li, Shun-Li
Tan, Ke
author_facet Li, Shun-Li
Tan, Ke
author_sort Li, Shun-Li
collection PubMed
description The title compound, bis­[2,2′-dimethyl-3,3′-(butane-1,4-di­yl)diimidazol-1-ium] β-octa­molybdate(VI), (C(12)H(20)N(4))(2)[Mo(8)O(26)], was produced by hydro­thermal reaction of an acidified aqueous solution of Na(2)MoO(4) and 1,4-bis­(2-methyl-1H-imidazol-1-yl)butane (hereafter L). The structure of the title compound consists of the β-octa­molybdate anions having a center of symmetry, and protonated [H(2) L](2+) cations, which link the β-octa­molybdate anions, generating a supra­molecular chain via hydrogen bonds.
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spelling pubmed-29601352010-12-30 A new β-octa­molybdate(VI) salt based on 1,4-bis­(2-methyl-1H-imidazol-1-yl)butane Li, Shun-Li Tan, Ke Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, bis­[2,2′-dimethyl-3,3′-(butane-1,4-di­yl)diimidazol-1-ium] β-octa­molybdate(VI), (C(12)H(20)N(4))(2)[Mo(8)O(26)], was produced by hydro­thermal reaction of an acidified aqueous solution of Na(2)MoO(4) and 1,4-bis­(2-methyl-1H-imidazol-1-yl)butane (hereafter L). The structure of the title compound consists of the β-octa­molybdate anions having a center of symmetry, and protonated [H(2) L](2+) cations, which link the β-octa­molybdate anions, generating a supra­molecular chain via hydrogen bonds. International Union of Crystallography 2008-11-08 /pmc/articles/PMC2960135/ /pubmed/21581111 http://dx.doi.org/10.1107/S1600536808035022 Text en © Li and Tan 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Shun-Li
Tan, Ke
A new β-octa­molybdate(VI) salt based on 1,4-bis­(2-methyl-1H-imidazol-1-yl)butane
title A new β-octa­molybdate(VI) salt based on 1,4-bis­(2-methyl-1H-imidazol-1-yl)butane
title_full A new β-octa­molybdate(VI) salt based on 1,4-bis­(2-methyl-1H-imidazol-1-yl)butane
title_fullStr A new β-octa­molybdate(VI) salt based on 1,4-bis­(2-methyl-1H-imidazol-1-yl)butane
title_full_unstemmed A new β-octa­molybdate(VI) salt based on 1,4-bis­(2-methyl-1H-imidazol-1-yl)butane
title_short A new β-octa­molybdate(VI) salt based on 1,4-bis­(2-methyl-1H-imidazol-1-yl)butane
title_sort new β-octa­molybdate(vi) salt based on 1,4-bis­(2-methyl-1h-imidazol-1-yl)butane
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960135/
https://www.ncbi.nlm.nih.gov/pubmed/21581111
http://dx.doi.org/10.1107/S1600536808035022
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