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Poly[4,4′-imino­dipyridinium [di-μ(4)-isophthalato-κ(4) O:O′:O′′:O′′-di-μ(3)-iso­phthal­ato-κ(3) O:O′:O′′;κ(4) O:O′:O′′,O′′′-trizinc(II)] dihydrate]

In the title compound, {(C(10)H(11)N(3))[Zn(3)(C(8)H(4)O(4))(4)]·2H(2)O}(n), divalent Zn atoms are linked into trinuclear units featuring tetra­hedral, octa­hedral and distorted tetrahedral, octahedral and square-pyramidal coordination geometries. These trinuclear units are connected by isopthalate...

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Detalles Bibliográficos
Autores principales: Braverman, Maxwell A., LaDuca, Robert L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960139/
https://www.ncbi.nlm.nih.gov/pubmed/21581198
http://dx.doi.org/10.1107/S1600536808038373
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author Braverman, Maxwell A.
LaDuca, Robert L.
author_facet Braverman, Maxwell A.
LaDuca, Robert L.
author_sort Braverman, Maxwell A.
collection PubMed
description In the title compound, {(C(10)H(11)N(3))[Zn(3)(C(8)H(4)O(4))(4)]·2H(2)O}(n), divalent Zn atoms are linked into trinuclear units featuring tetra­hedral, octa­hedral and distorted tetrahedral, octahedral and square-pyramidal coordination geometries. These trinuclear units are connected by isopthalate dianions into [Zn(3)(isophthalate)(4)](n) (2n−) anionic layers, which aggregate into the three-dimensional structure via hydrogen-bonding pathways mediated by doubly protonated 4,4′-imino­dipyridinium cations and water mol­ecules of crystallization. One solvent water mol­ecule was found to be disordered over two positions, each with a 50% site-occupancy factor.
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spelling pubmed-29601392010-12-30 Poly[4,4′-imino­dipyridinium [di-μ(4)-isophthalato-κ(4) O:O′:O′′:O′′-di-μ(3)-iso­phthal­ato-κ(3) O:O′:O′′;κ(4) O:O′:O′′,O′′′-trizinc(II)] dihydrate] Braverman, Maxwell A. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {(C(10)H(11)N(3))[Zn(3)(C(8)H(4)O(4))(4)]·2H(2)O}(n), divalent Zn atoms are linked into trinuclear units featuring tetra­hedral, octa­hedral and distorted tetrahedral, octahedral and square-pyramidal coordination geometries. These trinuclear units are connected by isopthalate dianions into [Zn(3)(isophthalate)(4)](n) (2n−) anionic layers, which aggregate into the three-dimensional structure via hydrogen-bonding pathways mediated by doubly protonated 4,4′-imino­dipyridinium cations and water mol­ecules of crystallization. One solvent water mol­ecule was found to be disordered over two positions, each with a 50% site-occupancy factor. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2960139/ /pubmed/21581198 http://dx.doi.org/10.1107/S1600536808038373 Text en © Braverman and LaDuca 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Braverman, Maxwell A.
LaDuca, Robert L.
Poly[4,4′-imino­dipyridinium [di-μ(4)-isophthalato-κ(4) O:O′:O′′:O′′-di-μ(3)-iso­phthal­ato-κ(3) O:O′:O′′;κ(4) O:O′:O′′,O′′′-trizinc(II)] dihydrate]
title Poly[4,4′-imino­dipyridinium [di-μ(4)-isophthalato-κ(4) O:O′:O′′:O′′-di-μ(3)-iso­phthal­ato-κ(3) O:O′:O′′;κ(4) O:O′:O′′,O′′′-trizinc(II)] dihydrate]
title_full Poly[4,4′-imino­dipyridinium [di-μ(4)-isophthalato-κ(4) O:O′:O′′:O′′-di-μ(3)-iso­phthal­ato-κ(3) O:O′:O′′;κ(4) O:O′:O′′,O′′′-trizinc(II)] dihydrate]
title_fullStr Poly[4,4′-imino­dipyridinium [di-μ(4)-isophthalato-κ(4) O:O′:O′′:O′′-di-μ(3)-iso­phthal­ato-κ(3) O:O′:O′′;κ(4) O:O′:O′′,O′′′-trizinc(II)] dihydrate]
title_full_unstemmed Poly[4,4′-imino­dipyridinium [di-μ(4)-isophthalato-κ(4) O:O′:O′′:O′′-di-μ(3)-iso­phthal­ato-κ(3) O:O′:O′′;κ(4) O:O′:O′′,O′′′-trizinc(II)] dihydrate]
title_short Poly[4,4′-imino­dipyridinium [di-μ(4)-isophthalato-κ(4) O:O′:O′′:O′′-di-μ(3)-iso­phthal­ato-κ(3) O:O′:O′′;κ(4) O:O′:O′′,O′′′-trizinc(II)] dihydrate]
title_sort poly[4,4′-imino­dipyridinium [di-μ(4)-isophthalato-κ(4) o:o′:o′′:o′′-di-μ(3)-iso­phthal­ato-κ(3) o:o′:o′′;κ(4) o:o′:o′′,o′′′-trizinc(ii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960139/
https://www.ncbi.nlm.nih.gov/pubmed/21581198
http://dx.doi.org/10.1107/S1600536808038373
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