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Poly[4,4′-iminodipyridinium [di-μ(4)-isophthalato-κ(4) O:O′:O′′:O′′-di-μ(3)-isophthalato-κ(3) O:O′:O′′;κ(4) O:O′:O′′,O′′′-trizinc(II)] dihydrate]
In the title compound, {(C(10)H(11)N(3))[Zn(3)(C(8)H(4)O(4))(4)]·2H(2)O}(n), divalent Zn atoms are linked into trinuclear units featuring tetrahedral, octahedral and distorted tetrahedral, octahedral and square-pyramidal coordination geometries. These trinuclear units are connected by isopthalate...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960139/ https://www.ncbi.nlm.nih.gov/pubmed/21581198 http://dx.doi.org/10.1107/S1600536808038373 |
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author | Braverman, Maxwell A. LaDuca, Robert L. |
author_facet | Braverman, Maxwell A. LaDuca, Robert L. |
author_sort | Braverman, Maxwell A. |
collection | PubMed |
description | In the title compound, {(C(10)H(11)N(3))[Zn(3)(C(8)H(4)O(4))(4)]·2H(2)O}(n), divalent Zn atoms are linked into trinuclear units featuring tetrahedral, octahedral and distorted tetrahedral, octahedral and square-pyramidal coordination geometries. These trinuclear units are connected by isopthalate dianions into [Zn(3)(isophthalate)(4)](n) (2n−) anionic layers, which aggregate into the three-dimensional structure via hydrogen-bonding pathways mediated by doubly protonated 4,4′-iminodipyridinium cations and water molecules of crystallization. One solvent water molecule was found to be disordered over two positions, each with a 50% site-occupancy factor. |
format | Text |
id | pubmed-2960139 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29601392010-12-30 Poly[4,4′-iminodipyridinium [di-μ(4)-isophthalato-κ(4) O:O′:O′′:O′′-di-μ(3)-isophthalato-κ(3) O:O′:O′′;κ(4) O:O′:O′′,O′′′-trizinc(II)] dihydrate] Braverman, Maxwell A. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {(C(10)H(11)N(3))[Zn(3)(C(8)H(4)O(4))(4)]·2H(2)O}(n), divalent Zn atoms are linked into trinuclear units featuring tetrahedral, octahedral and distorted tetrahedral, octahedral and square-pyramidal coordination geometries. These trinuclear units are connected by isopthalate dianions into [Zn(3)(isophthalate)(4)](n) (2n−) anionic layers, which aggregate into the three-dimensional structure via hydrogen-bonding pathways mediated by doubly protonated 4,4′-iminodipyridinium cations and water molecules of crystallization. One solvent water molecule was found to be disordered over two positions, each with a 50% site-occupancy factor. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2960139/ /pubmed/21581198 http://dx.doi.org/10.1107/S1600536808038373 Text en © Braverman and LaDuca 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Braverman, Maxwell A. LaDuca, Robert L. Poly[4,4′-iminodipyridinium [di-μ(4)-isophthalato-κ(4) O:O′:O′′:O′′-di-μ(3)-isophthalato-κ(3) O:O′:O′′;κ(4) O:O′:O′′,O′′′-trizinc(II)] dihydrate] |
title | Poly[4,4′-iminodipyridinium [di-μ(4)-isophthalato-κ(4)
O:O′:O′′:O′′-di-μ(3)-isophthalato-κ(3)
O:O′:O′′;κ(4)
O:O′:O′′,O′′′-trizinc(II)] dihydrate] |
title_full | Poly[4,4′-iminodipyridinium [di-μ(4)-isophthalato-κ(4)
O:O′:O′′:O′′-di-μ(3)-isophthalato-κ(3)
O:O′:O′′;κ(4)
O:O′:O′′,O′′′-trizinc(II)] dihydrate] |
title_fullStr | Poly[4,4′-iminodipyridinium [di-μ(4)-isophthalato-κ(4)
O:O′:O′′:O′′-di-μ(3)-isophthalato-κ(3)
O:O′:O′′;κ(4)
O:O′:O′′,O′′′-trizinc(II)] dihydrate] |
title_full_unstemmed | Poly[4,4′-iminodipyridinium [di-μ(4)-isophthalato-κ(4)
O:O′:O′′:O′′-di-μ(3)-isophthalato-κ(3)
O:O′:O′′;κ(4)
O:O′:O′′,O′′′-trizinc(II)] dihydrate] |
title_short | Poly[4,4′-iminodipyridinium [di-μ(4)-isophthalato-κ(4)
O:O′:O′′:O′′-di-μ(3)-isophthalato-κ(3)
O:O′:O′′;κ(4)
O:O′:O′′,O′′′-trizinc(II)] dihydrate] |
title_sort | poly[4,4′-iminodipyridinium [di-μ(4)-isophthalato-κ(4)
o:o′:o′′:o′′-di-μ(3)-isophthalato-κ(3)
o:o′:o′′;κ(4)
o:o′:o′′,o′′′-trizinc(ii)] dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960139/ https://www.ncbi.nlm.nih.gov/pubmed/21581198 http://dx.doi.org/10.1107/S1600536808038373 |
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