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5-(4-Chlorophenyl)-1-(2,4-dichlorophenyl)-4-methyl-1H-pyrazole-3-carboxylic acid
The asymmetric unit of the title compound, C(17)H(11)Cl(3)N(2)O(2), contains two independent molecules; the pyrazole rings are oriented with respect to the chlorophenyl and dichlorophenyl rings at dihedral angles of 43.00 (3) and 65.06 (4)°, respectively, in one molecule, and 51.17 (3) and 69.99...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960141/ https://www.ncbi.nlm.nih.gov/pubmed/21581382 http://dx.doi.org/10.1107/S1600536808038105 |
Sumario: | The asymmetric unit of the title compound, C(17)H(11)Cl(3)N(2)O(2), contains two independent molecules; the pyrazole rings are oriented with respect to the chlorophenyl and dichlorophenyl rings at dihedral angles of 43.00 (3) and 65.06 (4)°, respectively, in one molecule, and 51.17 (3) and 69.99 (3)°, respectively, in the other. Pairs of intermolecular O—H⋯O hydrogen bonds link the molecules into dimers. In the crystal structure, there are π–π contacts between the pyrazole rings and dichlorophenyl rings [centroid–centroid distances = 3.859 (3) and 3.835 (3) Å]. |
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