(Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate benzoic acid solvate

In the title compound, [Ni(C(7)H(5)O(2))(C(16)H(36)N(4))]ClO(4)·C(7)H(6)O(2), the Ni atom displays a distorted octa­hedral coordination geometry with four N atoms of the ligand rac-5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane (L) in a folded configuration and two benzoate (bz) O a...

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Detalles Bibliográficos
Autores principales: Ou, Guang-Chuan, Zhang, Min, Yuan, Xian-You, Dai, Yong-Qiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960142/
https://www.ncbi.nlm.nih.gov/pubmed/21581188
http://dx.doi.org/10.1107/S1600536808038051
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author Ou, Guang-Chuan
Zhang, Min
Yuan, Xian-You
Dai, Yong-Qiang
author_facet Ou, Guang-Chuan
Zhang, Min
Yuan, Xian-You
Dai, Yong-Qiang
author_sort Ou, Guang-Chuan
collection PubMed
description In the title compound, [Ni(C(7)H(5)O(2))(C(16)H(36)N(4))]ClO(4)·C(7)H(6)O(2), the Ni atom displays a distorted octa­hedral coordination geometry with four N atoms of the ligand rac-5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane (L) in a folded configuration and two benzoate (bz) O atoms. The [Ni(rac-L)(bz)](+) complex cation, perchlorate anion and benzoic acid mol­ecules engage in hydrogen bonding, with N⋯O distances between 2.970 (3) and 3.123 (3) Å and an O⋯O distance of 2.691 (3) Å.
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spelling pubmed-29601422010-12-30 (Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate benzoic acid solvate Ou, Guang-Chuan Zhang, Min Yuan, Xian-You Dai, Yong-Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(7)H(5)O(2))(C(16)H(36)N(4))]ClO(4)·C(7)H(6)O(2), the Ni atom displays a distorted octa­hedral coordination geometry with four N atoms of the ligand rac-5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane (L) in a folded configuration and two benzoate (bz) O atoms. The [Ni(rac-L)(bz)](+) complex cation, perchlorate anion and benzoic acid mol­ecules engage in hydrogen bonding, with N⋯O distances between 2.970 (3) and 3.123 (3) Å and an O⋯O distance of 2.691 (3) Å. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2960142/ /pubmed/21581188 http://dx.doi.org/10.1107/S1600536808038051 Text en © Ou et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ou, Guang-Chuan
Zhang, Min
Yuan, Xian-You
Dai, Yong-Qiang
(Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate benzoic acid solvate
title (Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate benzoic acid solvate
title_full (Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate benzoic acid solvate
title_fullStr (Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate benzoic acid solvate
title_full_unstemmed (Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate benzoic acid solvate
title_short (Benzoato-κ(2) O,O′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)nickel(II) perchlorate benzoic acid solvate
title_sort (benzoato-κ(2) o,o′)(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) n,n′,n′′,n′′′)nickel(ii) perchlorate benzoic acid solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960142/
https://www.ncbi.nlm.nih.gov/pubmed/21581188
http://dx.doi.org/10.1107/S1600536808038051
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AT yuanxianyou benzoatok2oo557121214hexamethyl14811tetraazacyclotetradecanek4nnnnnickeliiperchloratebenzoicacidsolvate
AT daiyongqiang benzoatok2oo557121214hexamethyl14811tetraazacyclotetradecanek4nnnnnickeliiperchloratebenzoicacidsolvate

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