Bis(2-methyl-4-nitro­anilinium) tetra­chloridomercurate(II)

The title compound, (C(7)H(9)N(2)O(2))(2)[HgCl(4)], self-assembles into cationic organic bilayers containing the 2-methyl-4-nitro­anilinium cations, sandwiched between anionic inorganic layers built up by the distorted tetra­hedral [HgCl(4)](2−) groups. The organic sheets are inter­linked through we...

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Detalles Bibliográficos
Autores principales: Dinesh, Jasrotia, Rademeyer, Melanie, Billing, David G., Lemmerer, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960147/
https://www.ncbi.nlm.nih.gov/pubmed/21581195
http://dx.doi.org/10.1107/S1600536808038415
Descripción
Sumario:The title compound, (C(7)H(9)N(2)O(2))(2)[HgCl(4)], self-assembles into cationic organic bilayers containing the 2-methyl-4-nitro­anilinium cations, sandwiched between anionic inorganic layers built up by the distorted tetra­hedral [HgCl(4)](2−) groups. The organic sheets are inter­linked through weak C—H⋯O hydrogen bonds, while they inter­act with the anionic part via strong charge-assisted N(+)—H⋯Cl—Hg hydrogen bonds. The [HgCl(4)](2−) anions are bis­ected by a mirror plane passing through the metal and two of the chloride ions.

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