Bis(2-methyl-4-nitro­anilinium) tetra­chloridomercurate(II)

The title compound, (C(7)H(9)N(2)O(2))(2)[HgCl(4)], self-assembles into cationic organic bilayers containing the 2-methyl-4-nitro­anilinium cations, sandwiched between anionic inorganic layers built up by the distorted tetra­hedral [HgCl(4)](2−) groups. The organic sheets are inter­linked through we...

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Detalles Bibliográficos
Autores principales: Dinesh, Jasrotia, Rademeyer, Melanie, Billing, David G., Lemmerer, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960147/
https://www.ncbi.nlm.nih.gov/pubmed/21581195
http://dx.doi.org/10.1107/S1600536808038415
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author Dinesh, Jasrotia
Rademeyer, Melanie
Billing, David G.
Lemmerer, Andreas
author_facet Dinesh, Jasrotia
Rademeyer, Melanie
Billing, David G.
Lemmerer, Andreas
author_sort Dinesh, Jasrotia
collection PubMed
description The title compound, (C(7)H(9)N(2)O(2))(2)[HgCl(4)], self-assembles into cationic organic bilayers containing the 2-methyl-4-nitro­anilinium cations, sandwiched between anionic inorganic layers built up by the distorted tetra­hedral [HgCl(4)](2−) groups. The organic sheets are inter­linked through weak C—H⋯O hydrogen bonds, while they inter­act with the anionic part via strong charge-assisted N(+)—H⋯Cl—Hg hydrogen bonds. The [HgCl(4)](2−) anions are bis­ected by a mirror plane passing through the metal and two of the chloride ions.
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spelling pubmed-29601472010-12-30 Bis(2-methyl-4-nitro­anilinium) tetra­chloridomercurate(II) Dinesh, Jasrotia Rademeyer, Melanie Billing, David G. Lemmerer, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(7)H(9)N(2)O(2))(2)[HgCl(4)], self-assembles into cationic organic bilayers containing the 2-methyl-4-nitro­anilinium cations, sandwiched between anionic inorganic layers built up by the distorted tetra­hedral [HgCl(4)](2−) groups. The organic sheets are inter­linked through weak C—H⋯O hydrogen bonds, while they inter­act with the anionic part via strong charge-assisted N(+)—H⋯Cl—Hg hydrogen bonds. The [HgCl(4)](2−) anions are bis­ected by a mirror plane passing through the metal and two of the chloride ions. International Union of Crystallography 2008-11-22 /pmc/articles/PMC2960147/ /pubmed/21581195 http://dx.doi.org/10.1107/S1600536808038415 Text en © Dinesh et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dinesh, Jasrotia
Rademeyer, Melanie
Billing, David G.
Lemmerer, Andreas
Bis(2-methyl-4-nitro­anilinium) tetra­chloridomercurate(II)
title Bis(2-methyl-4-nitro­anilinium) tetra­chloridomercurate(II)
title_full Bis(2-methyl-4-nitro­anilinium) tetra­chloridomercurate(II)
title_fullStr Bis(2-methyl-4-nitro­anilinium) tetra­chloridomercurate(II)
title_full_unstemmed Bis(2-methyl-4-nitro­anilinium) tetra­chloridomercurate(II)
title_short Bis(2-methyl-4-nitro­anilinium) tetra­chloridomercurate(II)
title_sort bis(2-methyl-4-nitro­anilinium) tetra­chloridomercurate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960147/
https://www.ncbi.nlm.nih.gov/pubmed/21581195
http://dx.doi.org/10.1107/S1600536808038415
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