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(1R,2R,3R,4R,5S)-2,3-Bis[(2S′)-2-acet­oxy-2-phenyl­acet­oxy]-4-azido-1-[(2,4-dinitro­phen­yl)hydrazono­meth­yl]bicyclo­[3.1.0]hexa­ne

In the title compound, C(38)H(29)N(7)O(12), the five-membered ring adopts an envelope conformation in which the ‘flap’ is cis to the cyclo­propane group. This conformation is similar to those of other bicyclo­[3.1.0]hexane analogues for which crystal structures have been reported. The absolute confi...

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Detalles Bibliográficos
Autores principales: Li, Jing, Lowary, Todd L., McDonald, Robert
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960152/
https://www.ncbi.nlm.nih.gov/pubmed/21201486
http://dx.doi.org/10.1107/S1600536808000718
Descripción
Sumario:In the title compound, C(38)H(29)N(7)O(12), the five-membered ring adopts an envelope conformation in which the ‘flap’ is cis to the cyclo­propane group. This conformation is similar to those of other bicyclo­[3.1.0]hexane analogues for which crystal structures have been reported. The absolute configuration of the stereogenic centers on the cyclo­pentane ring, as determined by comparison with the known configurations of the stereogenic centers in the (2S)-2-acet­oxy-2-phenyl­acet­oxy groups, is 1(R), 2(R), 3(R), 4(R) and 5(S). An intramolecular N—H⋯O hydrogen bond is present.