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(Glycol-κ(2) O,O′)nitros­yl(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) bis­(tri­fluoro­methane­sulfonate)

The title compound, [Ru(C(10)H(15))(NO)(HOCH(2)CH(2)OH)](CF(3)SO(3))(2), possesses a three-legged piano-stool geometry around the Ru atom, with an average Ru—O distance of 2.120 (6) Å and an Ru—N—O angle of 159.45 (14)°. The ethyl­eneglycol ligand forms a non-planar metallacyclic ring by chelating t...

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Detalles Bibliográficos
Autores principales: Munie, Semeret, Larsen, Anna, Gembicky, Milan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960154/
https://www.ncbi.nlm.nih.gov/pubmed/21201270
http://dx.doi.org/10.1107/S1600536807067426
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author Munie, Semeret
Larsen, Anna
Gembicky, Milan
author_facet Munie, Semeret
Larsen, Anna
Gembicky, Milan
author_sort Munie, Semeret
collection PubMed
description The title compound, [Ru(C(10)H(15))(NO)(HOCH(2)CH(2)OH)](CF(3)SO(3))(2), possesses a three-legged piano-stool geometry around the Ru atom, with an average Ru—O distance of 2.120 (6) Å and an Ru—N—O angle of 159.45 (14)°. The ethyl­eneglycol ligand forms a non-planar metallacyclic ring by chelating the Ru atom via the O atoms. The O⋯O distances of 2.554 (2) and 2.568 (2) Å are indicative of hydrogen bonding between coordinated ethyl­eneglycol and outer-sphere trifluoro­methane­sulfonate fragments. The crystal packing is stabilized by ionic forces and several CH(3)⋯·F (2.585 and 2.640 Å) and CH(3)⋯O inter­actions (2.391, 2.678, 2.694 and 2.699 Å) between the penta­methyl­cyclo­penta­dienyl ligand and trifluoro­methane­sulfonate anion. There is noticeable short inter­molecular contact [2.9039 (16) Å], between an O atom of the SO(3) group and a C atom of the penta­methyl­cyclo­penta­dienyl ligand.
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spelling pubmed-29601542010-12-30 (Glycol-κ(2) O,O′)nitros­yl(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) bis­(tri­fluoro­methane­sulfonate) Munie, Semeret Larsen, Anna Gembicky, Milan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ru(C(10)H(15))(NO)(HOCH(2)CH(2)OH)](CF(3)SO(3))(2), possesses a three-legged piano-stool geometry around the Ru atom, with an average Ru—O distance of 2.120 (6) Å and an Ru—N—O angle of 159.45 (14)°. The ethyl­eneglycol ligand forms a non-planar metallacyclic ring by chelating the Ru atom via the O atoms. The O⋯O distances of 2.554 (2) and 2.568 (2) Å are indicative of hydrogen bonding between coordinated ethyl­eneglycol and outer-sphere trifluoro­methane­sulfonate fragments. The crystal packing is stabilized by ionic forces and several CH(3)⋯·F (2.585 and 2.640 Å) and CH(3)⋯O inter­actions (2.391, 2.678, 2.694 and 2.699 Å) between the penta­methyl­cyclo­penta­dienyl ligand and trifluoro­methane­sulfonate anion. There is noticeable short inter­molecular contact [2.9039 (16) Å], between an O atom of the SO(3) group and a C atom of the penta­methyl­cyclo­penta­dienyl ligand. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960154/ /pubmed/21201270 http://dx.doi.org/10.1107/S1600536807067426 Text en © Munie et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Munie, Semeret
Larsen, Anna
Gembicky, Milan
(Glycol-κ(2) O,O′)nitros­yl(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) bis­(tri­fluoro­methane­sulfonate)
title (Glycol-κ(2) O,O′)nitros­yl(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) bis­(tri­fluoro­methane­sulfonate)
title_full (Glycol-κ(2) O,O′)nitros­yl(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) bis­(tri­fluoro­methane­sulfonate)
title_fullStr (Glycol-κ(2) O,O′)nitros­yl(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) bis­(tri­fluoro­methane­sulfonate)
title_full_unstemmed (Glycol-κ(2) O,O′)nitros­yl(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) bis­(tri­fluoro­methane­sulfonate)
title_short (Glycol-κ(2) O,O′)nitros­yl(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) bis­(tri­fluoro­methane­sulfonate)
title_sort (glycol-κ(2) o,o′)nitros­yl(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(ii) bis­(tri­fluoro­methane­sulfonate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960154/
https://www.ncbi.nlm.nih.gov/pubmed/21201270
http://dx.doi.org/10.1107/S1600536807067426
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AT gembickymilan glycolk2oonitrosylē5pentamethylcyclopentadienylrutheniumiibistrifluoromethanesulfonate