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(Glycol-κ(2) O,O′)nitrosyl(η(5)-pentamethylcyclopentadienyl)ruthenium(II) bis(trifluoromethanesulfonate)
The title compound, [Ru(C(10)H(15))(NO)(HOCH(2)CH(2)OH)](CF(3)SO(3))(2), possesses a three-legged piano-stool geometry around the Ru atom, with an average Ru—O distance of 2.120 (6) Å and an Ru—N—O angle of 159.45 (14)°. The ethyleneglycol ligand forms a non-planar metallacyclic ring by chelating t...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960154/ https://www.ncbi.nlm.nih.gov/pubmed/21201270 http://dx.doi.org/10.1107/S1600536807067426 |
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author | Munie, Semeret Larsen, Anna Gembicky, Milan |
author_facet | Munie, Semeret Larsen, Anna Gembicky, Milan |
author_sort | Munie, Semeret |
collection | PubMed |
description | The title compound, [Ru(C(10)H(15))(NO)(HOCH(2)CH(2)OH)](CF(3)SO(3))(2), possesses a three-legged piano-stool geometry around the Ru atom, with an average Ru—O distance of 2.120 (6) Å and an Ru—N—O angle of 159.45 (14)°. The ethyleneglycol ligand forms a non-planar metallacyclic ring by chelating the Ru atom via the O atoms. The O⋯O distances of 2.554 (2) and 2.568 (2) Å are indicative of hydrogen bonding between coordinated ethyleneglycol and outer-sphere trifluoromethanesulfonate fragments. The crystal packing is stabilized by ionic forces and several CH(3)⋯·F (2.585 and 2.640 Å) and CH(3)⋯O interactions (2.391, 2.678, 2.694 and 2.699 Å) between the pentamethylcyclopentadienyl ligand and trifluoromethanesulfonate anion. There is noticeable short intermolecular contact [2.9039 (16) Å], between an O atom of the SO(3) group and a C atom of the pentamethylcyclopentadienyl ligand. |
format | Text |
id | pubmed-2960154 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29601542010-12-30 (Glycol-κ(2) O,O′)nitrosyl(η(5)-pentamethylcyclopentadienyl)ruthenium(II) bis(trifluoromethanesulfonate) Munie, Semeret Larsen, Anna Gembicky, Milan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ru(C(10)H(15))(NO)(HOCH(2)CH(2)OH)](CF(3)SO(3))(2), possesses a three-legged piano-stool geometry around the Ru atom, with an average Ru—O distance of 2.120 (6) Å and an Ru—N—O angle of 159.45 (14)°. The ethyleneglycol ligand forms a non-planar metallacyclic ring by chelating the Ru atom via the O atoms. The O⋯O distances of 2.554 (2) and 2.568 (2) Å are indicative of hydrogen bonding between coordinated ethyleneglycol and outer-sphere trifluoromethanesulfonate fragments. The crystal packing is stabilized by ionic forces and several CH(3)⋯·F (2.585 and 2.640 Å) and CH(3)⋯O interactions (2.391, 2.678, 2.694 and 2.699 Å) between the pentamethylcyclopentadienyl ligand and trifluoromethanesulfonate anion. There is noticeable short intermolecular contact [2.9039 (16) Å], between an O atom of the SO(3) group and a C atom of the pentamethylcyclopentadienyl ligand. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960154/ /pubmed/21201270 http://dx.doi.org/10.1107/S1600536807067426 Text en © Munie et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Munie, Semeret Larsen, Anna Gembicky, Milan (Glycol-κ(2) O,O′)nitrosyl(η(5)-pentamethylcyclopentadienyl)ruthenium(II) bis(trifluoromethanesulfonate) |
title | (Glycol-κ(2)
O,O′)nitrosyl(η(5)-pentamethylcyclopentadienyl)ruthenium(II) bis(trifluoromethanesulfonate) |
title_full | (Glycol-κ(2)
O,O′)nitrosyl(η(5)-pentamethylcyclopentadienyl)ruthenium(II) bis(trifluoromethanesulfonate) |
title_fullStr | (Glycol-κ(2)
O,O′)nitrosyl(η(5)-pentamethylcyclopentadienyl)ruthenium(II) bis(trifluoromethanesulfonate) |
title_full_unstemmed | (Glycol-κ(2)
O,O′)nitrosyl(η(5)-pentamethylcyclopentadienyl)ruthenium(II) bis(trifluoromethanesulfonate) |
title_short | (Glycol-κ(2)
O,O′)nitrosyl(η(5)-pentamethylcyclopentadienyl)ruthenium(II) bis(trifluoromethanesulfonate) |
title_sort | (glycol-κ(2)
o,o′)nitrosyl(η(5)-pentamethylcyclopentadienyl)ruthenium(ii) bis(trifluoromethanesulfonate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960154/ https://www.ncbi.nlm.nih.gov/pubmed/21201270 http://dx.doi.org/10.1107/S1600536807067426 |
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