cis-Difluoridobis(1,10-phenanthroline)chromium(III) perchlorate monohydrate

The title complex, [CrF(2)(C(12)H(8)N(2))(2)]ClO(4)·H(2)O, displays a slightly distorted octa­hedral coordination geometry around the central chromium(III) ion. The Cr environment is composed of a cis arrangement of two 1,10-phenanthroline [average Cr(III)—N = 2.0726 (10) Å] and two fluoride [averag...

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Detalles Bibliográficos
Autores principales: Birk, Torben, Bendix, Jesper, Weihe, Högni
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960161/
https://www.ncbi.nlm.nih.gov/pubmed/21201326
http://dx.doi.org/10.1107/S1600536808001153
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author Birk, Torben
Bendix, Jesper
Weihe, Högni
author_facet Birk, Torben
Bendix, Jesper
Weihe, Högni
author_sort Birk, Torben
collection PubMed
description The title complex, [CrF(2)(C(12)H(8)N(2))(2)]ClO(4)·H(2)O, displays a slightly distorted octa­hedral coordination geometry around the central chromium(III) ion. The Cr environment is composed of a cis arrangement of two 1,10-phenanthroline [average Cr(III)—N = 2.0726 (10) Å] and two fluoride [average Cr(III)—F = 1.8533 (6) Å] ligands. The water molecule forms a hydrogen bond to fluorine in a neighbouring cation.
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spelling pubmed-29601612010-12-30 cis-Difluoridobis(1,10-phenanthroline)chromium(III) perchlorate monohydrate Birk, Torben Bendix, Jesper Weihe, Högni Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [CrF(2)(C(12)H(8)N(2))(2)]ClO(4)·H(2)O, displays a slightly distorted octa­hedral coordination geometry around the central chromium(III) ion. The Cr environment is composed of a cis arrangement of two 1,10-phenanthroline [average Cr(III)—N = 2.0726 (10) Å] and two fluoride [average Cr(III)—F = 1.8533 (6) Å] ligands. The water molecule forms a hydrogen bond to fluorine in a neighbouring cation. International Union of Crystallography 2008-01-16 /pmc/articles/PMC2960161/ /pubmed/21201326 http://dx.doi.org/10.1107/S1600536808001153 Text en © Birk et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Birk, Torben
Bendix, Jesper
Weihe, Högni
cis-Difluoridobis(1,10-phenanthroline)chromium(III) perchlorate monohydrate
title cis-Difluoridobis(1,10-phenanthroline)chromium(III) perchlorate monohydrate
title_full cis-Difluoridobis(1,10-phenanthroline)chromium(III) perchlorate monohydrate
title_fullStr cis-Difluoridobis(1,10-phenanthroline)chromium(III) perchlorate monohydrate
title_full_unstemmed cis-Difluoridobis(1,10-phenanthroline)chromium(III) perchlorate monohydrate
title_short cis-Difluoridobis(1,10-phenanthroline)chromium(III) perchlorate monohydrate
title_sort cis-difluoridobis(1,10-phenanthroline)chromium(iii) perchlorate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960161/
https://www.ncbi.nlm.nih.gov/pubmed/21201326
http://dx.doi.org/10.1107/S1600536808001153
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