trans-Carbon­yl[dihydro­bis(1,2,4-triazol-1-yl-κN (2))borato]hydridobis(triphenyl­phosphine-κP)ruthenium(II) acetonitrile solvate

In the crystal structure of the title compound, [Ru(C(4)H(6)BN(6))H(C(18)H(15)P)(2)(CO)]·C(2)H(3)N, discrete mononuclear complexes are found in which the Ru atom is coordinated by two triphenyl­phosphine (PPh(3)) ligands, one dihydro­bis(1,2,4-triazol-1-yl)borate ligand, one carbonyl ligand and one...

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Detalles Bibliográficos
Autor principal: Huh, Seong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960167/
https://www.ncbi.nlm.nih.gov/pubmed/21201268
http://dx.doi.org/10.1107/S160053680706792X
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author Huh, Seong
author_facet Huh, Seong
author_sort Huh, Seong
collection PubMed
description In the crystal structure of the title compound, [Ru(C(4)H(6)BN(6))H(C(18)H(15)P)(2)(CO)]·C(2)H(3)N, discrete mononuclear complexes are found in which the Ru atom is coordinated by two triphenyl­phosphine (PPh(3)) ligands, one dihydro­bis(1,2,4-triazol-1-yl)borate ligand, one carbonyl ligand and one hydride atom within slightly distorted octa­hedra. The two P atoms of the PPh(3) ligands are trans positioned and the two N atoms of the chelating dihydro­bis(1,2,4-triazol-1-yl)borate ligand occupy cis positions.
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spelling pubmed-29601672010-12-30 trans-Carbon­yl[dihydro­bis(1,2,4-triazol-1-yl-κN (2))borato]hydridobis(triphenyl­phosphine-κP)ruthenium(II) acetonitrile solvate Huh, Seong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Ru(C(4)H(6)BN(6))H(C(18)H(15)P)(2)(CO)]·C(2)H(3)N, discrete mononuclear complexes are found in which the Ru atom is coordinated by two triphenyl­phosphine (PPh(3)) ligands, one dihydro­bis(1,2,4-triazol-1-yl)borate ligand, one carbonyl ligand and one hydride atom within slightly distorted octa­hedra. The two P atoms of the PPh(3) ligands are trans positioned and the two N atoms of the chelating dihydro­bis(1,2,4-triazol-1-yl)borate ligand occupy cis positions. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960167/ /pubmed/21201268 http://dx.doi.org/10.1107/S160053680706792X Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Huh, Seong
trans-Carbon­yl[dihydro­bis(1,2,4-triazol-1-yl-κN (2))borato]hydridobis(triphenyl­phosphine-κP)ruthenium(II) acetonitrile solvate
title trans-Carbon­yl[dihydro­bis(1,2,4-triazol-1-yl-κN (2))borato]hydridobis(triphenyl­phosphine-κP)ruthenium(II) acetonitrile solvate
title_full trans-Carbon­yl[dihydro­bis(1,2,4-triazol-1-yl-κN (2))borato]hydridobis(triphenyl­phosphine-κP)ruthenium(II) acetonitrile solvate
title_fullStr trans-Carbon­yl[dihydro­bis(1,2,4-triazol-1-yl-κN (2))borato]hydridobis(triphenyl­phosphine-κP)ruthenium(II) acetonitrile solvate
title_full_unstemmed trans-Carbon­yl[dihydro­bis(1,2,4-triazol-1-yl-κN (2))borato]hydridobis(triphenyl­phosphine-κP)ruthenium(II) acetonitrile solvate
title_short trans-Carbon­yl[dihydro­bis(1,2,4-triazol-1-yl-κN (2))borato]hydridobis(triphenyl­phosphine-κP)ruthenium(II) acetonitrile solvate
title_sort trans-carbon­yl[dihydro­bis(1,2,4-triazol-1-yl-κn (2))borato]hydridobis(triphenyl­phosphine-κp)ruthenium(ii) acetonitrile solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960167/
https://www.ncbi.nlm.nih.gov/pubmed/21201268
http://dx.doi.org/10.1107/S160053680706792X
work_keys_str_mv AT huhseong transcarbonyldihydrobis124triazol1ylkn2boratohydridobistriphenylphosphinekprutheniumiiacetonitrilesolvate

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