Cargando…
Aqua(4-methylquinoline-κN)[N-(2-oxidobenzylidene)glycinato-κ(3) O,N,O′]copper(II) hemihydrate
The title complex, [Cu(C(9)H(7)NO(3))(C(10)H(9)N)(H(2)O)]·0.5H(2)O, crystallizes with two independent formula units in the asymmetric unit; the solvent molecule is located on a twofold axis of symmetry. The Cu(II) atom is coordinated by one tridentate N-salicylideneglycinate Schiff base ligand, one...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960168/ https://www.ncbi.nlm.nih.gov/pubmed/21201263 http://dx.doi.org/10.1107/S1600536807067852 |
Sumario: | The title complex, [Cu(C(9)H(7)NO(3))(C(10)H(9)N)(H(2)O)]·0.5H(2)O, crystallizes with two independent formula units in the asymmetric unit; the solvent molecule is located on a twofold axis of symmetry. The Cu(II) atom is coordinated by one tridentate N-salicylideneglycinate Schiff base ligand, one 4-methylquinoline ligand and one water molecule, leading to a slightly distorted square-pyramidal N(2)O(3) geometry. In the crystal structure, the molecules are linked by O—H⋯O hydrogen bonds into linear chains in the [100] direction. The structure is further stabilized by intermolecular C—H⋯O interactions and C⋯C contacts with C⋯C = 3.3058 (2), 3.3636 (2) and 3.3946 (2) Å. |
---|