Aqua­(4-methyl­quinoline-κN)[N-(2-oxidobenzyl­idene)glycinato-κ(3) O,N,O′]copper(II) hemihydrate

The title complex, [Cu(C(9)H(7)NO(3))(C(10)H(9)N)(H(2)O)]·0.5H(2)O, crystallizes with two independent formula units in the asymmetric unit; the solvent mol­ecule is located on a twofold axis of symmetry. The Cu(II) atom is coordinated by one tridentate N-salicylideneglycinate Schiff base ligand, one...

Descripción completa

Detalles Bibliográficos
Autores principales: Trávníček, Zdeněk, Marek, Jaromír, Vančo, Ján, Švajlenová, Oľga
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960168/
https://www.ncbi.nlm.nih.gov/pubmed/21201263
http://dx.doi.org/10.1107/S1600536807067852
_version_ 1782188674604072960
author Trávníček, Zdeněk
Marek, Jaromír
Vančo, Ján
Švajlenová, Oľga
author_facet Trávníček, Zdeněk
Marek, Jaromír
Vančo, Ján
Švajlenová, Oľga
author_sort Trávníček, Zdeněk
collection PubMed
description The title complex, [Cu(C(9)H(7)NO(3))(C(10)H(9)N)(H(2)O)]·0.5H(2)O, crystallizes with two independent formula units in the asymmetric unit; the solvent mol­ecule is located on a twofold axis of symmetry. The Cu(II) atom is coordinated by one tridentate N-salicylideneglycinate Schiff base ligand, one 4-methyl­quinoline ligand and one water mol­ecule, leading to a slightly distorted square-pyramidal N(2)O(3) geometry. In the crystal structure, the mol­ecules are linked by O—H⋯O hydrogen bonds into linear chains in the [100] direction. The structure is further stabilized by inter­molecular C—H⋯O inter­actions and C⋯C contacts with C⋯C = 3.3058 (2), 3.3636 (2) and 3.3946 (2) Å.
format Text
id pubmed-2960168
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29601682010-12-30 Aqua­(4-methyl­quinoline-κN)[N-(2-oxidobenzyl­idene)glycinato-κ(3) O,N,O′]copper(II) hemihydrate Trávníček, Zdeněk Marek, Jaromír Vančo, Ján Švajlenová, Oľga Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(C(9)H(7)NO(3))(C(10)H(9)N)(H(2)O)]·0.5H(2)O, crystallizes with two independent formula units in the asymmetric unit; the solvent mol­ecule is located on a twofold axis of symmetry. The Cu(II) atom is coordinated by one tridentate N-salicylideneglycinate Schiff base ligand, one 4-methyl­quinoline ligand and one water mol­ecule, leading to a slightly distorted square-pyramidal N(2)O(3) geometry. In the crystal structure, the mol­ecules are linked by O—H⋯O hydrogen bonds into linear chains in the [100] direction. The structure is further stabilized by inter­molecular C—H⋯O inter­actions and C⋯C contacts with C⋯C = 3.3058 (2), 3.3636 (2) and 3.3946 (2) Å. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960168/ /pubmed/21201263 http://dx.doi.org/10.1107/S1600536807067852 Text en © Trávníček et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Trávníček, Zdeněk
Marek, Jaromír
Vančo, Ján
Švajlenová, Oľga
Aqua­(4-methyl­quinoline-κN)[N-(2-oxidobenzyl­idene)glycinato-κ(3) O,N,O′]copper(II) hemihydrate
title Aqua­(4-methyl­quinoline-κN)[N-(2-oxidobenzyl­idene)glycinato-κ(3) O,N,O′]copper(II) hemihydrate
title_full Aqua­(4-methyl­quinoline-κN)[N-(2-oxidobenzyl­idene)glycinato-κ(3) O,N,O′]copper(II) hemihydrate
title_fullStr Aqua­(4-methyl­quinoline-κN)[N-(2-oxidobenzyl­idene)glycinato-κ(3) O,N,O′]copper(II) hemihydrate
title_full_unstemmed Aqua­(4-methyl­quinoline-κN)[N-(2-oxidobenzyl­idene)glycinato-κ(3) O,N,O′]copper(II) hemihydrate
title_short Aqua­(4-methyl­quinoline-κN)[N-(2-oxidobenzyl­idene)glycinato-κ(3) O,N,O′]copper(II) hemihydrate
title_sort aqua­(4-methyl­quinoline-κn)[n-(2-oxidobenzyl­idene)glycinato-κ(3) o,n,o′]copper(ii) hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960168/
https://www.ncbi.nlm.nih.gov/pubmed/21201263
http://dx.doi.org/10.1107/S1600536807067852
work_keys_str_mv AT travnicekzdenek aqua4methylquinolineknn2oxidobenzylideneglycinatok3onocopperiihemihydrate
AT marekjaromir aqua4methylquinolineknn2oxidobenzylideneglycinatok3onocopperiihemihydrate
AT vancojan aqua4methylquinolineknn2oxidobenzylideneglycinatok3onocopperiihemihydrate
AT svajlenovaolga aqua4methylquinolineknn2oxidobenzylideneglycinatok3onocopperiihemihydrate

Ejemplares similares