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catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxylato]
In the title compound, [Co(C(14)H(8)O(4))(C(18)H(10)N(4))](n), the Co(II) atom is six-coordinated by four O atoms from two different biphenyl-2,2′-dicarboxylate ligands and two N atoms from the bidentate dipyrido[3,2-a:2′,3′-c]phenazine ligand in a distorted octahedral geometry. The Co(II) atoms a...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960172/ https://www.ncbi.nlm.nih.gov/pubmed/21201334 http://dx.doi.org/10.1107/S1600536808001827 |
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author | Wei, Fang Wang, Wen-Ju Jin, Xiang-Jun Mei, Ze-Min Li, Xiao-Ping |
author_facet | Wei, Fang Wang, Wen-Ju Jin, Xiang-Jun Mei, Ze-Min Li, Xiao-Ping |
author_sort | Wei, Fang |
collection | PubMed |
description | In the title compound, [Co(C(14)H(8)O(4))(C(18)H(10)N(4))](n), the Co(II) atom is six-coordinated by four O atoms from two different biphenyl-2,2′-dicarboxylate ligands and two N atoms from the bidentate dipyrido[3,2-a:2′,3′-c]phenazine ligand in a distorted octahedral geometry. The Co(II) atoms are bridged by the biphenyl-2,2′-dicarboxylate ligands to form a one-dimensional chain structure. π–π interactions between neighbouring chains result in a two-dimensional supramolecular network (centroid-to-centroid separation = 3.381 Å). |
format | Text |
id | pubmed-2960172 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29601722010-12-30 catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxylato] Wei, Fang Wang, Wen-Ju Jin, Xiang-Jun Mei, Ze-Min Li, Xiao-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(14)H(8)O(4))(C(18)H(10)N(4))](n), the Co(II) atom is six-coordinated by four O atoms from two different biphenyl-2,2′-dicarboxylate ligands and two N atoms from the bidentate dipyrido[3,2-a:2′,3′-c]phenazine ligand in a distorted octahedral geometry. The Co(II) atoms are bridged by the biphenyl-2,2′-dicarboxylate ligands to form a one-dimensional chain structure. π–π interactions between neighbouring chains result in a two-dimensional supramolecular network (centroid-to-centroid separation = 3.381 Å). International Union of Crystallography 2008-01-23 /pmc/articles/PMC2960172/ /pubmed/21201334 http://dx.doi.org/10.1107/S1600536808001827 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Wei, Fang Wang, Wen-Ju Jin, Xiang-Jun Mei, Ze-Min Li, Xiao-Ping catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxylato] |
title |
catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxylato] |
title_full |
catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxylato] |
title_fullStr |
catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxylato] |
title_full_unstemmed |
catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxylato] |
title_short |
catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxylato] |
title_sort | catena-poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(ii)]-μ-biphenyl-2,2′-dicarboxylato] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960172/ https://www.ncbi.nlm.nih.gov/pubmed/21201334 http://dx.doi.org/10.1107/S1600536808001827 |
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