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catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxyl­ato]

In the title compound, [Co(C(14)H(8)O(4))(C(18)H(10)N(4))](n), the Co(II) atom is six-coordinated by four O atoms from two different biphenyl-2,2′-dicarboxyl­ate ligands and two N atoms from the bidentate dipyrido[3,2-a:2′,3′-c]phenazine ligand in a distorted octa­hedral geometry. The Co(II) atoms a...

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Detalles Bibliográficos
Autores principales: Wei, Fang, Wang, Wen-Ju, Jin, Xiang-Jun, Mei, Ze-Min, Li, Xiao-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960172/
https://www.ncbi.nlm.nih.gov/pubmed/21201334
http://dx.doi.org/10.1107/S1600536808001827
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author Wei, Fang
Wang, Wen-Ju
Jin, Xiang-Jun
Mei, Ze-Min
Li, Xiao-Ping
author_facet Wei, Fang
Wang, Wen-Ju
Jin, Xiang-Jun
Mei, Ze-Min
Li, Xiao-Ping
author_sort Wei, Fang
collection PubMed
description In the title compound, [Co(C(14)H(8)O(4))(C(18)H(10)N(4))](n), the Co(II) atom is six-coordinated by four O atoms from two different biphenyl-2,2′-dicarboxyl­ate ligands and two N atoms from the bidentate dipyrido[3,2-a:2′,3′-c]phenazine ligand in a distorted octa­hedral geometry. The Co(II) atoms are bridged by the biphenyl-2,2′-dicarboxyl­ate ligands to form a one-dimensional chain structure. π–π inter­actions between neighbouring chains result in a two-dimensional supra­molecular network (centroid-to-centroid separation = 3.381 Å).
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spelling pubmed-29601722010-12-30 catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxyl­ato] Wei, Fang Wang, Wen-Ju Jin, Xiang-Jun Mei, Ze-Min Li, Xiao-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(14)H(8)O(4))(C(18)H(10)N(4))](n), the Co(II) atom is six-coordinated by four O atoms from two different biphenyl-2,2′-dicarboxyl­ate ligands and two N atoms from the bidentate dipyrido[3,2-a:2′,3′-c]phenazine ligand in a distorted octa­hedral geometry. The Co(II) atoms are bridged by the biphenyl-2,2′-dicarboxyl­ate ligands to form a one-dimensional chain structure. π–π inter­actions between neighbouring chains result in a two-dimensional supra­molecular network (centroid-to-centroid separation = 3.381 Å). International Union of Crystallography 2008-01-23 /pmc/articles/PMC2960172/ /pubmed/21201334 http://dx.doi.org/10.1107/S1600536808001827 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Wei, Fang
Wang, Wen-Ju
Jin, Xiang-Jun
Mei, Ze-Min
Li, Xiao-Ping
catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxyl­ato]
title catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxyl­ato]
title_full catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxyl­ato]
title_fullStr catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxyl­ato]
title_full_unstemmed catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxyl­ato]
title_short catena-Poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(II)]-μ-biphenyl-2,2′-dicarboxyl­ato]
title_sort catena-poly[[(dipyrido[3,2-a:2′,3′-c]phenazine)cobalt(ii)]-μ-biphenyl-2,2′-dicarboxyl­ato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960172/
https://www.ncbi.nlm.nih.gov/pubmed/21201334
http://dx.doi.org/10.1107/S1600536808001827
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