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N,N′-{[Bis(trifluoro­meth­yl)methyl­ene]di-p-phenyl­ene}diphthalimide

The molecule of the title compound, C(31)H(16)F(6)N(2)O(4), consists of two phthalimide units linked by a [bis­(trifluoro­meth­yl)methyl­ene]di-p-phenyl­ene bridge, with the two halves of the mol­ecule related to each other by a twofold rotation axis. The dihedral angle between the planes of the two...

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Detalles Bibliográficos
Autores principales: Li, Yitao, Wang, Zhiguo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960178/
https://www.ncbi.nlm.nih.gov/pubmed/21201418
http://dx.doi.org/10.1107/S1600536807068249
Descripción
Sumario:The molecule of the title compound, C(31)H(16)F(6)N(2)O(4), consists of two phthalimide units linked by a [bis­(trifluoro­meth­yl)methyl­ene]di-p-phenyl­ene bridge, with the two halves of the mol­ecule related to each other by a twofold rotation axis. The dihedral angle between the planes of the two central benzene rings is 70.5 (3)°. The terminal isoindole groups are approximately planar, with a maximum r.m.s. deviation of 0.006 Å from the mean plane, and they form dihedral angles of 46.03 (3)° to the attached benzene rings. Inter­molecular C—H⋯O hydrogen bonds link neighboring mol­ecules into chains along the c axis.