N,N′-{[Bis(trifluoro­meth­yl)methyl­ene]di-p-phenyl­ene}diphthalimide

The molecule of the title compound, C(31)H(16)F(6)N(2)O(4), consists of two phthalimide units linked by a [bis­(trifluoro­meth­yl)methyl­ene]di-p-phenyl­ene bridge, with the two halves of the mol­ecule related to each other by a twofold rotation axis. The dihedral angle between the planes of the two...

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Detalles Bibliográficos
Autores principales: Li, Yitao, Wang, Zhiguo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960178/
https://www.ncbi.nlm.nih.gov/pubmed/21201418
http://dx.doi.org/10.1107/S1600536807068249
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author Li, Yitao
Wang, Zhiguo
author_facet Li, Yitao
Wang, Zhiguo
author_sort Li, Yitao
collection PubMed
description The molecule of the title compound, C(31)H(16)F(6)N(2)O(4), consists of two phthalimide units linked by a [bis­(trifluoro­meth­yl)methyl­ene]di-p-phenyl­ene bridge, with the two halves of the mol­ecule related to each other by a twofold rotation axis. The dihedral angle between the planes of the two central benzene rings is 70.5 (3)°. The terminal isoindole groups are approximately planar, with a maximum r.m.s. deviation of 0.006 Å from the mean plane, and they form dihedral angles of 46.03 (3)° to the attached benzene rings. Inter­molecular C—H⋯O hydrogen bonds link neighboring mol­ecules into chains along the c axis.
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spelling pubmed-29601782010-12-30 N,N′-{[Bis(trifluoro­meth­yl)methyl­ene]di-p-phenyl­ene}diphthalimide Li, Yitao Wang, Zhiguo Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(31)H(16)F(6)N(2)O(4), consists of two phthalimide units linked by a [bis­(trifluoro­meth­yl)methyl­ene]di-p-phenyl­ene bridge, with the two halves of the mol­ecule related to each other by a twofold rotation axis. The dihedral angle between the planes of the two central benzene rings is 70.5 (3)°. The terminal isoindole groups are approximately planar, with a maximum r.m.s. deviation of 0.006 Å from the mean plane, and they form dihedral angles of 46.03 (3)° to the attached benzene rings. Inter­molecular C—H⋯O hydrogen bonds link neighboring mol­ecules into chains along the c axis. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960178/ /pubmed/21201418 http://dx.doi.org/10.1107/S1600536807068249 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Li, Yitao
Wang, Zhiguo
N,N′-{[Bis(trifluoro­meth­yl)methyl­ene]di-p-phenyl­ene}diphthalimide
title N,N′-{[Bis(trifluoro­meth­yl)methyl­ene]di-p-phenyl­ene}diphthalimide
title_full N,N′-{[Bis(trifluoro­meth­yl)methyl­ene]di-p-phenyl­ene}diphthalimide
title_fullStr N,N′-{[Bis(trifluoro­meth­yl)methyl­ene]di-p-phenyl­ene}diphthalimide
title_full_unstemmed N,N′-{[Bis(trifluoro­meth­yl)methyl­ene]di-p-phenyl­ene}diphthalimide
title_short N,N′-{[Bis(trifluoro­meth­yl)methyl­ene]di-p-phenyl­ene}diphthalimide
title_sort n,n′-{[bis(trifluoro­meth­yl)methyl­ene]di-p-phenyl­ene}diphthalimide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960178/
https://www.ncbi.nlm.nih.gov/pubmed/21201418
http://dx.doi.org/10.1107/S1600536807068249
work_keys_str_mv AT liyitao nnbistrifluoromethylmethylenedipphenylenediphthalimide
AT wangzhiguo nnbistrifluoromethylmethylenedipphenylenediphthalimide

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