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Aqua(4,5-dihydroxybenzene-1,3-disulfonato-κO)bis(1,10-phenanthroline-κ(2) N,N’)cadmium(II) monohydrate
In the title compound, [Cd(C(6)H(4)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)]·H(2)O, each Cd(II) ion is coordinated by four N atoms [Cd—N = 2.310 (7)–2.341 (7) Å] from two 1,10-phenanthroline ligands, one O atom [Cd—O = 2.300 (6) Å] from a 4,5-dihydroxybenzene-1,3-disulfonate ligand and one aqua O atom [C...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960182/ https://www.ncbi.nlm.nih.gov/pubmed/21201347 http://dx.doi.org/10.1107/S1600536807067918 |
| Sumario: | In the title compound, [Cd(C(6)H(4)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)]·H(2)O, each Cd(II) ion is coordinated by four N atoms [Cd—N = 2.310 (7)–2.341 (7) Å] from two 1,10-phenanthroline ligands, one O atom [Cd—O = 2.300 (6) Å] from a 4,5-dihydroxybenzene-1,3-disulfonate ligand and one aqua O atom [Cd—O = 2.288 (7) Å] in a distorted octahedral geometry. The crystal packing exhibits intermolecular O—H⋯O and C—H⋯O hydrogen bonds and π–π interactions evidenced by relatively short distances [3.525 (5)–3.937 (6) Å] between the centroids of the six-membered rings of neighbouring molecules. |
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