Aqua­(4,5-dihydroxy­benzene-1,3-disulfonato-κO)bis­(1,10-phenanthroline-κ(2) N,N’)cadmium(II) monohydrate

In the title compound, [Cd(C(6)H(4)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)]·H(2)O, each Cd(II) ion is coordinated by four N atoms [Cd—N = 2.310 (7)–2.341 (7) Å] from two 1,10-phenanthroline ligands, one O atom [Cd—O = 2.300 (6) Å] from a 4,5-dihydroxy­benzene-1,3-disulfonate ligand and one aqua O atom [C...

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Detalles Bibliográficos
Autores principales: Zhang, Xiangdong, Ge, Chunhua, Guan, Lei, Sun, Zhimin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960182/
https://www.ncbi.nlm.nih.gov/pubmed/21201347
http://dx.doi.org/10.1107/S1600536807067918
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author Zhang, Xiangdong
Ge, Chunhua
Guan, Lei
Sun, Zhimin
author_facet Zhang, Xiangdong
Ge, Chunhua
Guan, Lei
Sun, Zhimin
author_sort Zhang, Xiangdong
collection PubMed
description In the title compound, [Cd(C(6)H(4)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)]·H(2)O, each Cd(II) ion is coordinated by four N atoms [Cd—N = 2.310 (7)–2.341 (7) Å] from two 1,10-phenanthroline ligands, one O atom [Cd—O = 2.300 (6) Å] from a 4,5-dihydroxy­benzene-1,3-disulfonate ligand and one aqua O atom [Cd—O = 2.288 (7) Å] in a distorted octa­hedral geometry. The crystal packing exhibits inter­molecular O—H⋯O and C—H⋯O hydrogen bonds and π–π inter­actions evidenced by relatively short distances [3.525 (5)–3.937 (6) Å] between the centroids of the six-membered rings of neighbouring mol­ecules.
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spelling pubmed-29601822010-12-30 Aqua­(4,5-dihydroxy­benzene-1,3-disulfonato-κO)bis­(1,10-phenanthroline-κ(2) N,N’)cadmium(II) monohydrate Zhang, Xiangdong Ge, Chunhua Guan, Lei Sun, Zhimin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(6)H(4)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)]·H(2)O, each Cd(II) ion is coordinated by four N atoms [Cd—N = 2.310 (7)–2.341 (7) Å] from two 1,10-phenanthroline ligands, one O atom [Cd—O = 2.300 (6) Å] from a 4,5-dihydroxy­benzene-1,3-disulfonate ligand and one aqua O atom [Cd—O = 2.288 (7) Å] in a distorted octa­hedral geometry. The crystal packing exhibits inter­molecular O—H⋯O and C—H⋯O hydrogen bonds and π–π inter­actions evidenced by relatively short distances [3.525 (5)–3.937 (6) Å] between the centroids of the six-membered rings of neighbouring mol­ecules. International Union of Crystallography 2008-01-23 /pmc/articles/PMC2960182/ /pubmed/21201347 http://dx.doi.org/10.1107/S1600536807067918 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Xiangdong
Ge, Chunhua
Guan, Lei
Sun, Zhimin
Aqua­(4,5-dihydroxy­benzene-1,3-disulfonato-κO)bis­(1,10-phenanthroline-κ(2) N,N’)cadmium(II) monohydrate
title Aqua­(4,5-dihydroxy­benzene-1,3-disulfonato-κO)bis­(1,10-phenanthroline-κ(2) N,N’)cadmium(II) monohydrate
title_full Aqua­(4,5-dihydroxy­benzene-1,3-disulfonato-κO)bis­(1,10-phenanthroline-κ(2) N,N’)cadmium(II) monohydrate
title_fullStr Aqua­(4,5-dihydroxy­benzene-1,3-disulfonato-κO)bis­(1,10-phenanthroline-κ(2) N,N’)cadmium(II) monohydrate
title_full_unstemmed Aqua­(4,5-dihydroxy­benzene-1,3-disulfonato-κO)bis­(1,10-phenanthroline-κ(2) N,N’)cadmium(II) monohydrate
title_short Aqua­(4,5-dihydroxy­benzene-1,3-disulfonato-κO)bis­(1,10-phenanthroline-κ(2) N,N’)cadmium(II) monohydrate
title_sort aqua­(4,5-dihydroxy­benzene-1,3-disulfonato-κo)bis­(1,10-phenanthroline-κ(2) n,n’)cadmium(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960182/
https://www.ncbi.nlm.nih.gov/pubmed/21201347
http://dx.doi.org/10.1107/S1600536807067918
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AT guanlei aqua45dihydroxybenzene13disulfonatokobis110phenanthrolinek2nncadmiumiimonohydrate
AT sunzhimin aqua45dihydroxybenzene13disulfonatokobis110phenanthrolinek2nncadmiumiimonohydrate

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