(E)-N-[2-(9-Fluorenyl­idene)-3a,5,7-tri­methyl-3,3a-dihydro-2H-indol-3-yl­idene]-2,4,6-trimethyl­aniline

The title compound, C(33)H(30)N(2), has an E configuration at the imine double bond. The angle between the least-squares planes of the imine C=N—C group and the benzene ring of the 2,4,6-trimethylphenyl substituent is 85.38 (11)°. The crystal structure is sustained mainly by inter­molecular π–π inte...

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Detalles Bibliográficos
Autores principales: Mizuhata, Yoshiyuki, Tokitoh, Norihiro
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960190/
https://www.ncbi.nlm.nih.gov/pubmed/21201516
http://dx.doi.org/10.1107/S1600536808001657
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author Mizuhata, Yoshiyuki
Tokitoh, Norihiro
author_facet Mizuhata, Yoshiyuki
Tokitoh, Norihiro
author_sort Mizuhata, Yoshiyuki
collection PubMed
description The title compound, C(33)H(30)N(2), has an E configuration at the imine double bond. The angle between the least-squares planes of the imine C=N—C group and the benzene ring of the 2,4,6-trimethylphenyl substituent is 85.38 (11)°. The crystal structure is sustained mainly by inter­molecular π–π inter­actions (3.510 Å) between the two fluorene rings and some C—H⋯π inter­actions.
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spelling pubmed-29601902010-12-30 (E)-N-[2-(9-Fluorenyl­idene)-3a,5,7-tri­methyl-3,3a-dihydro-2H-indol-3-yl­idene]-2,4,6-trimethyl­aniline Mizuhata, Yoshiyuki Tokitoh, Norihiro Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(33)H(30)N(2), has an E configuration at the imine double bond. The angle between the least-squares planes of the imine C=N—C group and the benzene ring of the 2,4,6-trimethylphenyl substituent is 85.38 (11)°. The crystal structure is sustained mainly by inter­molecular π–π inter­actions (3.510 Å) between the two fluorene rings and some C—H⋯π inter­actions. International Union of Crystallography 2008-01-23 /pmc/articles/PMC2960190/ /pubmed/21201516 http://dx.doi.org/10.1107/S1600536808001657 Text en © Mizuhata and Tokitoh 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mizuhata, Yoshiyuki
Tokitoh, Norihiro
(E)-N-[2-(9-Fluorenyl­idene)-3a,5,7-tri­methyl-3,3a-dihydro-2H-indol-3-yl­idene]-2,4,6-trimethyl­aniline
title (E)-N-[2-(9-Fluorenyl­idene)-3a,5,7-tri­methyl-3,3a-dihydro-2H-indol-3-yl­idene]-2,4,6-trimethyl­aniline
title_full (E)-N-[2-(9-Fluorenyl­idene)-3a,5,7-tri­methyl-3,3a-dihydro-2H-indol-3-yl­idene]-2,4,6-trimethyl­aniline
title_fullStr (E)-N-[2-(9-Fluorenyl­idene)-3a,5,7-tri­methyl-3,3a-dihydro-2H-indol-3-yl­idene]-2,4,6-trimethyl­aniline
title_full_unstemmed (E)-N-[2-(9-Fluorenyl­idene)-3a,5,7-tri­methyl-3,3a-dihydro-2H-indol-3-yl­idene]-2,4,6-trimethyl­aniline
title_short (E)-N-[2-(9-Fluorenyl­idene)-3a,5,7-tri­methyl-3,3a-dihydro-2H-indol-3-yl­idene]-2,4,6-trimethyl­aniline
title_sort (e)-n-[2-(9-fluorenyl­idene)-3a,5,7-tri­methyl-3,3a-dihydro-2h-indol-3-yl­idene]-2,4,6-trimethyl­aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960190/
https://www.ncbi.nlm.nih.gov/pubmed/21201516
http://dx.doi.org/10.1107/S1600536808001657
work_keys_str_mv AT mizuhatayoshiyuki en29fluorenylidene3a57trimethyl33adihydro2hindol3ylidene246trimethylaniline
AT tokitohnorihiro en29fluorenylidene3a57trimethyl33adihydro2hindol3ylidene246trimethylaniline

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