Tricarbonyl­chlorido{N-[2-(diphenyl­phosphino)benzyl­idene]benzyl­amine-κ(2) N,P}rhenium(I) dichloro­methane solvate

In the crystal structure of the title compound, [ReCl(C(26)H(22)NP)(CO)(3)]·CH(2)Cl(2), the Re(I) atom exhibits a distorted octa­hedral environment defined by a facial arrangement of three carbonyl groups, a Cl atom and an N-[2-(diphenyl­phosphino)benzyl­idene]benzyl­amine ligand. The compound cryst...

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Detalles Bibliográficos
Autores principales: Monkowius, Uwe, Zabel, Manfred
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960194/
https://www.ncbi.nlm.nih.gov/pubmed/21201284
http://dx.doi.org/10.1107/S160053680706802X
Descripción
Sumario:In the crystal structure of the title compound, [ReCl(C(26)H(22)NP)(CO)(3)]·CH(2)Cl(2), the Re(I) atom exhibits a distorted octa­hedral environment defined by a facial arrangement of three carbonyl groups, a Cl atom and an N-[2-(diphenyl­phosphino)benzyl­idene]benzyl­amine ligand. The compound crystallizes with one CH(2)Cl(2) mol­ecule per asymmetric unit. The benzyl­amine ligand and the Re(I) centre form a non-planar six-membered chelate ring.

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