Tricarbonyl­chlorido{N-[2-(diphenyl­phosphino)benzyl­idene]benzyl­amine-κ(2) N,P}rhenium(I) dichloro­methane solvate

In the crystal structure of the title compound, [ReCl(C(26)H(22)NP)(CO)(3)]·CH(2)Cl(2), the Re(I) atom exhibits a distorted octa­hedral environment defined by a facial arrangement of three carbonyl groups, a Cl atom and an N-[2-(diphenyl­phosphino)benzyl­idene]benzyl­amine ligand. The compound cryst...

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Detalles Bibliográficos
Autores principales: Monkowius, Uwe, Zabel, Manfred
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960194/
https://www.ncbi.nlm.nih.gov/pubmed/21201284
http://dx.doi.org/10.1107/S160053680706802X
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author Monkowius, Uwe
Zabel, Manfred
author_facet Monkowius, Uwe
Zabel, Manfred
author_sort Monkowius, Uwe
collection PubMed
description In the crystal structure of the title compound, [ReCl(C(26)H(22)NP)(CO)(3)]·CH(2)Cl(2), the Re(I) atom exhibits a distorted octa­hedral environment defined by a facial arrangement of three carbonyl groups, a Cl atom and an N-[2-(diphenyl­phosphino)benzyl­idene]benzyl­amine ligand. The compound crystallizes with one CH(2)Cl(2) mol­ecule per asymmetric unit. The benzyl­amine ligand and the Re(I) centre form a non-planar six-membered chelate ring.
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spelling pubmed-29601942010-12-30 Tricarbonyl­chlorido{N-[2-(diphenyl­phosphino)benzyl­idene]benzyl­amine-κ(2) N,P}rhenium(I) dichloro­methane solvate Monkowius, Uwe Zabel, Manfred Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [ReCl(C(26)H(22)NP)(CO)(3)]·CH(2)Cl(2), the Re(I) atom exhibits a distorted octa­hedral environment defined by a facial arrangement of three carbonyl groups, a Cl atom and an N-[2-(diphenyl­phosphino)benzyl­idene]benzyl­amine ligand. The compound crystallizes with one CH(2)Cl(2) mol­ecule per asymmetric unit. The benzyl­amine ligand and the Re(I) centre form a non-planar six-membered chelate ring. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960194/ /pubmed/21201284 http://dx.doi.org/10.1107/S160053680706802X Text en © Monkowius and Zabel 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Monkowius, Uwe
Zabel, Manfred
Tricarbonyl­chlorido{N-[2-(diphenyl­phosphino)benzyl­idene]benzyl­amine-κ(2) N,P}rhenium(I) dichloro­methane solvate
title Tricarbonyl­chlorido{N-[2-(diphenyl­phosphino)benzyl­idene]benzyl­amine-κ(2) N,P}rhenium(I) dichloro­methane solvate
title_full Tricarbonyl­chlorido{N-[2-(diphenyl­phosphino)benzyl­idene]benzyl­amine-κ(2) N,P}rhenium(I) dichloro­methane solvate
title_fullStr Tricarbonyl­chlorido{N-[2-(diphenyl­phosphino)benzyl­idene]benzyl­amine-κ(2) N,P}rhenium(I) dichloro­methane solvate
title_full_unstemmed Tricarbonyl­chlorido{N-[2-(diphenyl­phosphino)benzyl­idene]benzyl­amine-κ(2) N,P}rhenium(I) dichloro­methane solvate
title_short Tricarbonyl­chlorido{N-[2-(diphenyl­phosphino)benzyl­idene]benzyl­amine-κ(2) N,P}rhenium(I) dichloro­methane solvate
title_sort tricarbonyl­chlorido{n-[2-(diphenyl­phosphino)benzyl­idene]benzyl­amine-κ(2) n,p}rhenium(i) dichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960194/
https://www.ncbi.nlm.nih.gov/pubmed/21201284
http://dx.doi.org/10.1107/S160053680706802X
work_keys_str_mv AT monkowiusuwe tricarbonylchloridon2diphenylphosphinobenzylidenebenzylaminek2nprheniumidichloromethanesolvate
AT zabelmanfred tricarbonylchloridon2diphenylphosphinobenzylidenebenzylaminek2nprheniumidichloromethanesolvate

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