Bis(acetato-κO)[N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′]copper(II)

In the title compound, [Cu(C(2)H(3)O(2))(2)(C(6)H(16)N(2))], the Cu(II) atom is coordinated by two N atoms from the chelating N,N,N′,N′-tetra­methyl­ethane-1,2-diamine ligand and two O atoms from two acetate anions in a distorted square-planar geometry. In addition, there are longer contacts between...

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Detalles Bibliográficos
Autores principales: Slootweg, J. Chris, Chen, Peter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960195/
https://www.ncbi.nlm.nih.gov/pubmed/21201373
http://dx.doi.org/10.1107/S1600536808002584
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author Slootweg, J. Chris
Chen, Peter
author_facet Slootweg, J. Chris
Chen, Peter
author_sort Slootweg, J. Chris
collection PubMed
description In the title compound, [Cu(C(2)H(3)O(2))(2)(C(6)H(16)N(2))], the Cu(II) atom is coordinated by two N atoms from the chelating N,N,N′,N′-tetra­methyl­ethane-1,2-diamine ligand and two O atoms from two acetate anions in a distorted square-planar geometry. In addition, there are longer contacts between Cu and the second O atom of each acetate ligand, which could be considered to complete a distorted octa­hedral geometry. The mol­ecules in the crystal structure are connected via inter­molecular C—H⋯O hydrogen-bonding contacts.
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spelling pubmed-29601952010-12-30 Bis(acetato-κO)[N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′]copper(II) Slootweg, J. Chris Chen, Peter Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(2)H(3)O(2))(2)(C(6)H(16)N(2))], the Cu(II) atom is coordinated by two N atoms from the chelating N,N,N′,N′-tetra­methyl­ethane-1,2-diamine ligand and two O atoms from two acetate anions in a distorted square-planar geometry. In addition, there are longer contacts between Cu and the second O atom of each acetate ligand, which could be considered to complete a distorted octa­hedral geometry. The mol­ecules in the crystal structure are connected via inter­molecular C—H⋯O hydrogen-bonding contacts. International Union of Crystallography 2008-01-30 /pmc/articles/PMC2960195/ /pubmed/21201373 http://dx.doi.org/10.1107/S1600536808002584 Text en © Slootweg and Chen 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Slootweg, J. Chris
Chen, Peter
Bis(acetato-κO)[N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′]copper(II)
title Bis(acetato-κO)[N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′]copper(II)
title_full Bis(acetato-κO)[N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′]copper(II)
title_fullStr Bis(acetato-κO)[N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′]copper(II)
title_full_unstemmed Bis(acetato-κO)[N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′]copper(II)
title_short Bis(acetato-κO)[N,N,N′,N′-tetra­methyl­ethane-1,2-diamine-κ(2) N,N′]copper(II)
title_sort bis(acetato-κo)[n,n,n′,n′-tetra­methyl­ethane-1,2-diamine-κ(2) n,n′]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960195/
https://www.ncbi.nlm.nih.gov/pubmed/21201373
http://dx.doi.org/10.1107/S1600536808002584
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AT chenpeter bisacetatokonnnntetramethylethane12diaminek2nncopperii

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