Diaqua­bis(9-oxo-4,5-diaza­fluoren-3-olato-κ(2) N (4),O (3))cadmium(II)

The title compound, [Cd(C(11)H(5)N(2)O(2))(2)(H(2)O)(2)], is a mononuclear complex consisting of a Cd(II) atom, two 3-hydr­oxy-4,5-diaza­fluoren-9-one ligands and two coordinated water mol­ecules. The Cd(II) atom, lying on a twofold axis, displays a distorted octa­hedral coordintion. Adjacent mol­ec...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhao, Ya-Hui, Yuan, Xing, Qin, Wei-Chao, Sheng, Lian-Xi, Ding, Yun-Zheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960196/
https://www.ncbi.nlm.nih.gov/pubmed/21201251
http://dx.doi.org/10.1107/S1600536807067323
_version_ 1782188681291890688
author Zhao, Ya-Hui
Yuan, Xing
Qin, Wei-Chao
Sheng, Lian-Xi
Ding, Yun-Zheng
author_facet Zhao, Ya-Hui
Yuan, Xing
Qin, Wei-Chao
Sheng, Lian-Xi
Ding, Yun-Zheng
author_sort Zhao, Ya-Hui
collection PubMed
description The title compound, [Cd(C(11)H(5)N(2)O(2))(2)(H(2)O)(2)], is a mononuclear complex consisting of a Cd(II) atom, two 3-hydr­oxy-4,5-diaza­fluoren-9-one ligands and two coordinated water mol­ecules. The Cd(II) atom, lying on a twofold axis, displays a distorted octa­hedral coordintion. Adjacent mol­ecules are linked by O—H⋯O hydrogen bonds and π–π inter­actions [centroid–centroid distance = 3.84 (1) Å], leading to a one-dimensional chain. Weak C—H⋯O hydrogen bonds connect the chains into a two-dimensional supra­molecular structure.
format Text
id pubmed-2960196
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29601962010-12-30 Diaqua­bis(9-oxo-4,5-diaza­fluoren-3-olato-κ(2) N (4),O (3))cadmium(II) Zhao, Ya-Hui Yuan, Xing Qin, Wei-Chao Sheng, Lian-Xi Ding, Yun-Zheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(C(11)H(5)N(2)O(2))(2)(H(2)O)(2)], is a mononuclear complex consisting of a Cd(II) atom, two 3-hydr­oxy-4,5-diaza­fluoren-9-one ligands and two coordinated water mol­ecules. The Cd(II) atom, lying on a twofold axis, displays a distorted octa­hedral coordintion. Adjacent mol­ecules are linked by O—H⋯O hydrogen bonds and π–π inter­actions [centroid–centroid distance = 3.84 (1) Å], leading to a one-dimensional chain. Weak C—H⋯O hydrogen bonds connect the chains into a two-dimensional supra­molecular structure. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960196/ /pubmed/21201251 http://dx.doi.org/10.1107/S1600536807067323 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Zhao, Ya-Hui
Yuan, Xing
Qin, Wei-Chao
Sheng, Lian-Xi
Ding, Yun-Zheng
Diaqua­bis(9-oxo-4,5-diaza­fluoren-3-olato-κ(2) N (4),O (3))cadmium(II)
title Diaqua­bis(9-oxo-4,5-diaza­fluoren-3-olato-κ(2) N (4),O (3))cadmium(II)
title_full Diaqua­bis(9-oxo-4,5-diaza­fluoren-3-olato-κ(2) N (4),O (3))cadmium(II)
title_fullStr Diaqua­bis(9-oxo-4,5-diaza­fluoren-3-olato-κ(2) N (4),O (3))cadmium(II)
title_full_unstemmed Diaqua­bis(9-oxo-4,5-diaza­fluoren-3-olato-κ(2) N (4),O (3))cadmium(II)
title_short Diaqua­bis(9-oxo-4,5-diaza­fluoren-3-olato-κ(2) N (4),O (3))cadmium(II)
title_sort diaqua­bis(9-oxo-4,5-diaza­fluoren-3-olato-κ(2) n (4),o (3))cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960196/
https://www.ncbi.nlm.nih.gov/pubmed/21201251
http://dx.doi.org/10.1107/S1600536807067323
work_keys_str_mv AT zhaoyahui diaquabis9oxo45diazafluoren3olatok2n4o3cadmiumii
AT yuanxing diaquabis9oxo45diazafluoren3olatok2n4o3cadmiumii
AT qinweichao diaquabis9oxo45diazafluoren3olatok2n4o3cadmiumii
AT shenglianxi diaquabis9oxo45diazafluoren3olatok2n4o3cadmiumii
AT dingyunzheng diaquabis9oxo45diazafluoren3olatok2n4o3cadmiumii

Ejemplares similares